26670-16-6Relevant articles and documents
Polynuclear branched tetrazole systems. 3. Acidity of α,ω- ditetrazol-5-ylalkanes
Zubarev,Trifonov,Poborchii,Ostrovskii
, p. 469 - 474 (2006)
α,ω-Ditetrazol-5-ylalkanes with 1 to 5 methylene groups in the alkyl fragment display the properties of dibasic heterocyclic NH acids with pKa values lying in the range 3.4-6.1. The pKa values of these compounds are in a linear dependence on the values of the dielectric permeability of the medium, on the chemical shifts of the signals of the endocyclic carbon atom, and of the carbon atom of the α-methylene group in the 13C NMR spectra. 2006 Springer Science+Business Media, Inc.
Cocrystallization of photosensitive energetic copper(II) perchlorate complexes with the nitrogen-rich ligand 1,2-Di(1 H -tetrazol-5-yl)ethane
Evers, Jürgen,Gospodinov, Ivan,Joas, Manuel,Klap?tke, Thomas M.,Stierstorfer, J?rg
, p. 11749 - 11756 (2014)
Two recently introduced concepts in the design of new energetic materials, namely complexation and cocrystallization, have been applied in the synthesis and characterization of the energetic copper(II) compound [Cu(dt-5-e)2(H2O)](ClO4)2, which consists of two different complex cations and can be described as a model energetic ionic cocrystal. The presence of both the N-rich 1,2-di(1H-tetrazol-5-yl)ethane ligand and oxidizing perchlorate counterion results in a new type of energetic material. The ionic complex cocrystal consists of a mononuclear and a trinuclear complex unit. It can be obtained by precipitation from perchloric acid or by dehydration of the related mononuclear coordination compound [Cu(dt-5-e)2(H2O)2](ClO4)2·2H2O at 70 °C in the solid state. The transformation starting at 60 °C was monitored by X-ray powder diffraction and thermal analysis. The energetic ionic cocrystal was shown to be a new primary explosive suitable for laser ignition. The different coordination spheres within the ionic cocrystal (octahedral and square pyramidal) were shown by UV/vis/NIR spectroscopy to result in excellent light absorption.
Efficient transformation of inactive nitriles into 5-substituted 1 H-tetrazoles using microwave irradiation and their applications
Yoneyama, Hiroki,Usami, Yoshihide,Komeda, Seiji,Harusawa, Shinya
, p. 1051 - 1059 (2013/05/09)
Efficient transformations of inactive nitriles into 5-substituted 1H-tetrazoles in DMF in a microwave reactor are described. The present method is applied to the synthesis of tetrazolato-bridged dinuclear platinum(II) complex and tetrazole C1-ribonucleoside phosphoramidite. Georg Thieme Verlag Stuttgart, New York.