2689-59-0

Basic information

• Product Name: 2-furyl phenyl ketone
• Synonyms: 2-benzoylfuran;2-furyl phenyl ketone;(2-Furanyl) phenyl ketone;Phenyl (2-furyl) ketone;Phenyl 2-furyl ketone;furan-2-yl(phenyl)methanone
• CAS NO: 2689-59-0
• Molecular Formula: C₁₁H₈O₂
• Molecular Weight: 172.18
• Mol File: 2689-59-0.mol
• Article Data: 116

Chemical Properties

• Boiling Point: 285°C (estimate)
• Flash Point: 129°C
• Appearance: /
• Density: 1.1732
• Vapor Pressure: 0.00276mmHg at 25°C
• Refractive Index: 1.6055 (estimate)
• CAS DataBase Reference: 2-furyl phenyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-furyl phenyl ketone(2689-59-0)
• EPA Substance Registry System: 2-furyl phenyl ketone(2689-59-0)

Safety Data

• Hazardous Substances Data: 2689-59-0(Hazardous Substances Data)

Usage

General Description

2-furyl phenyl ketone, also known as 2-furyl benzophenone, is a chemical compound with the molecular formula C19H14O. It is a yellow crystalline solid with a sweet, floral aroma, and is commonly used in the production of perfumes and fragrance products. The compound is also found in some natural products, such as the essential oil of Costus oil, and has been identified as a potential bioactive molecule with anti-inflammatory and antioxidant properties. Additionally, 2-furyl phenyl ketone is used as a UV absorber in sunscreen and skincare products due to its ability to block harmful UV radiation. However,

InChI:InChI=1/C11H8O2/c12-11(10-7-4-8-13-10)9-5-2-1-3-6-9/h1-8H

Upstream product

• 110-00-9 furan 
• 455-32-3 benzoyl fluoride 
• 98-88-4 benzoyl chloride 
• 93-97-0 benzoic acid anhydride 
• 65-85-0 benzoic acid 
• 527-69-5 2-furancarbonyl chloride 
• 18163-75-2 trichloro-(furan-2-carbonyloxy)-silane 
• 71-43-2 benzene 
• 60-29-7 diethyl ether 
• 223431-27-4 N-ethyl-N-phenylfuran-2-carboxamide 
• 72667-24-4 Brenzschleimsaeurenitril 
• 100-47-0 benzonitrile 
• 2786-02-9 2-lithiofuran 
• 124-38-9 carbon dioxide 

Downstream Products

• 101273-89-6 [2]Furyl-phenyl-[2]pyridyl-methanol 
• 3308-02-9 3-hydroxy-2-phenylpyridine 
• 4481-56-5 α,α-diphenyl-2-furanmethanol 
• 82295-50-9 2,N-diphenylpyridinium betaine 
• 36169-60-5 1-[2]furyl-1,2-diphenyl-ethanol 
• 24965-41-1 1-[2]furyl-1-phenyl-prop-2-yn-1-ol 
• 141957-79-1 phenyl(tetrahydrofuran-2-yl)methanone 
• 51937-70-3 (5-nitro-furan-2-yl)-phenyl-methanone 
• 1450-01-7 (Z)-(furan-2-yl)phenylmethanone oxime 
• 2067-52-9 (E)-(furan-2-yl)phenylmethanone oxime 
• 968-68-3 1-furan-2-yl-4-morpholin-4-yl-1-phenyl-but-2-yn-1-ol 

Relevant articles and documents

Asymmetric Transfer Hydrogenation of Aryl Heteroaryl Ketones using Noyori-Ikariya Catalysts

A range of ketones flanked by a combination of an aromatic and a heterocyclic ring (furan, thiophene, N-methylimidazole) were reduced under asymmetric transfer hydrogenation (ATH) conditions. Using a range of [(arene)Ru(TsDPEN)Cl] precatalysts, including tethered derivatives, the reduction enantioselectivity was high (up to 99 % ee) in cases where the aromatic ring contained an ortho-substituent. The enantioselectivity is influenced by a combination of steric and electronic factors which for the furan and thiophene series, follow literature precedents. In the case of the N-methylimidazole-containing ketones, an unexpected switch in enantioselectivity took place upon variation of the opposing aromatic group. Pyrrole- containing ketones were resistant to reduction. This study demonstrates the asymmetric transfer hydrogenation (ATH) of a range of hindered heterocyclic ketones, in high conversion and ee, using Noyori-Ikariya catalysts.

Photoinduced remote heteroaryl migration accompanied by cyanoalkylacylation in continuous flow

A photoinduced 1,4-heteroaryl migration from a carbon center to a nitrogen center accompanied by a cyanoalkylacylation of heterocyclic-substituted azidyl homoallylic alcohols and cycloketone oxime esters has been described. This simple and powerful protoc

Novelmeta-benzothiazole and benzimidazole functionalised POCOP-Ni(ii) pincer complexes as efficient catalysts in the production of diarylketones

The synthesis of four novel non-symmetric Ni(ii)-POCOP pincer complexesmeta-functionalized with either benzothiazole or benzimidazole at the central aryl ring is described. All complexes were fully characterised in solution by various analytical techniques and the molecular structures in the solid state of complexes1b,2aand2bwere unequivocally determined by single crystal X-ray diffraction analysis. In addition, the Ni(ii)-POCOP pincer complexes were efficiently used as catalysts in the synthesis of diarylketones by cross-coupling reactions of functionalized benzaldehydes and boronic acid derivatives under relatively mild conditions. An important aspect of this transformation is the dependence on the steric properties of the donor groups (OPR2) of the pincer ligands, the more active compounds having the phosphinitos bearing isopropyl groups (1aand2a) than those containingtert-butyl substituents (1band2b).