26910-35-0

Basic information

• Product Name: Benzene, 1-[(bromomethyl)sulfinyl]-4-methyl-
• CAS NO: 26910-35-0
• Molecular Formula: C8H9BrOS
• Molecular Weight: 233.129
• Mol File: 26910-35-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(bromomethyl)sulfinyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(bromomethyl)sulfinyl]-4-methyl-(26910-35-0)
• EPA Substance Registry System: Benzene, 1-[(bromomethyl)sulfinyl]-4-methyl-(26910-35-0)

Safety Data

• Hazardous Substances Data: 26910-35-0(Hazardous Substances Data)

Upstream product

• 1519-39-7 (R)-(+)-methyl p-tolyl sulfoxide 
• 934-72-5 Methyl p-tolyl sulfoxide 

Downstream Products

• 35390-50-2 (+)-Methylthiomethyl-p-tolylsulfoxid 
• 35390-52-4 (+)-Ethoxymethyl-p-tolylsulfoxid 
• 1374153-87-3 (bromomethyl)(2,3,4,5-tetramethylphenyl)(p-tolyl)sulfonium triflate 
• 37891-95-5 bromomethyl 4-tolyl sulfone 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 17241-04-2 bis(p-tolylthio)methane 
• 35390-51-3 Phenylthiomethyl-p-tolylsulfoxid 
• 38111-68-1 Ethoxymethyl-p-tolylsulfenat 
• 35390-50-2 methylthiomethyl p-tolyl sulfoxide 
• 38010-00-3 α-Metoxymethyl-p-toluylsulfoxid 

Relevant articles and documents

ELECTROPHILIC REAGENTS FOR MONOHALOMETHYLATION,THEIR PREPARATION AND THEIR USES

The invention provides a compound of formula A, B, C or D, methods for making them, intermediates therefor, and their use in making organic biologically active compounds: (Formula (A)). Wherein: ? X = F, CI, Br, I, sulfonate esters, phosphate esters or another leaving group ? R1, R2, R3, R4, R5, R6, R7, R8, R9, R1O are each individually selected from H, alkyl, aryl, alkynyl, alkenyl, cycloalkyl, cycloalkenyl, alkoxy, nitro, halogen or amino; or are selected from H, C1C10 alkyl, aryl, C1C10 alkynyl, C1C10 alkenyl, C1C10 cycloalkyl, C1C10 cycloalkenyl, C1C10 alkoxy, nitro, halogen or amino ? R11 = tetrafluoroborate, triflate, halogen, perclorate, sulfates, phosphates or carbonates ? Excluding the case when: X = F and R1= R2 = R3 = R4= R5 = H and R6 R8 = R9 = methyl, R10 = H and R11 = triflate or tetrafluoroborate; or (Formula (B)). Wherein: X = F, CI, Br, I, sulfonate esters, phosphate esters or other another leaving group; and R1, R2, R3, R4, R5 are each individually selected from H, alkyl, aryl, alkynyl, alkenyl, cycloalkyl, cycloalkenyl, alkoxy, nitro, halogen or amino; or are selected from H, C1C10 alkyl, aryl, C1C10 alkynyl, C1C10 alkenyl, C1C10 cycloalkyl, C1C10 cycloalkenyl, C1C10 alkoxy, nitro, halogen or amino and R11 = tetrafluoroborate, triflate, halogen, perclorate, sulfates, phosphates or carbonates; and R12 = resin, naphthalene or substituted naphthalene Excluding the case when: X = F and R1= R2 = R3 = R4= R5 = H and R6 = R7 = R8 = R9 = methyl, R10 = H and R11 = triflate or tetrafluoroborate and when X = F and R1= R2 = R3 = R4= R5 = H and R12 = poly(styrene-co- divinylbenzene) and R11 = triflate or tetrafluoroborate; or (Formula (C)). Wehrein ? X = F, CI, Br, I, sulfonate esters, phosphate esters or another leaving group ? R13 = naphthalene or substituted naphthalene ? R6, R7, R8, R9, R10 are each individually selected from H, alkyl, aryl, alkynyl, alkenyl, cycloalkyl, cycloalkenyl, alcoxy, nitro, halogen or amino; or are selected from H, C1C10 alkyl, aryl, C1C10 alkynyl, C1C10 alkenyl, C1C10 cycloalkyl, C1C10 cycloalkenyl, C1C10 alkoxy, nitro, halogen or amino ? R11 = tetrafluoroborate, triflate, halogen, perclorate, sulfates, phosphates or carbonates: or (Formula (D)) X = F, CI, Br, I, sulfonate esters, phosphate esters or another leaving group R13 = naphthalene or substituted naphthalene R11 = tetrafluoroborate, triflate, halogen, perclorate, sulfates, phosphates carbonates R12 = resin, naphthalene or substituted naphthalene.