27151-74-2

Basic information

• Product Name: chloro(2-methylpropyl)mercury
• Synonyms: Isobutylmercuric chloride;Mercury,chloro(2-methylpropyl)-
• CAS NO: 27151-74-2
• Molecular Formula: C₄H₉ClHg
• Molecular Weight: 293.1573
• Mol File: 27151-74-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: chloro(2-methylpropyl)mercury(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(2-methylpropyl)mercury(27151-74-2)
• EPA Substance Registry System: chloro(2-methylpropyl)mercury(27151-74-2)

Safety Data

• Hazardous Substances Data: 27151-74-2(Hazardous Substances Data)

Upstream product

• 5674-02-2 2-methylpropylmagnesium chloride 

Downstream Products

• 13307-61-4 Isobutylthiobenzene 
• 24470-76-6 diisobutylmercury 
• 67773-54-0 bis(1-norbornyl)mercury 

Relevant articles and documents

UEBER EINE trans-EINFLUSS-REIHE DER ORGANYLANIONEN AUS 13C-NMR-SPEKTROSKOPISCHEN UNTERSUCHUNGEN VON ORGANYLQUECKSILBERISOBUTYLVERBINDUNGEN

The 1J(199Hg-13C) coupling constants of isobutylmercury compounds RHgCH2CHMe2 (R=organo group) have been measured and compared to the coupling constants of diisobutylmercury and diorganomercury compounds HgR2.Between the coupling constants 1J(Hg-Ci-Bu) and 1J(Hg-CR), which have been normalized to the coupling constants of the symmetric compounds concerned, a linear relation has been found.This relation, which can be deduced from the Fermi contact term on the basis of the simple hybrid orbital model, shows that the coupling constant 1J(Hg-Ci-Bu) reflects the s-character of the mercury hybrid orbital concerned and accordingly the NMR trans-influence of the organo group R.The NMR trans-influence decreases in the sequence t-Bu > i-Pr ca. cyclo-C6H11 > Et ca. n-Pr ca. n-Bu ca. i-Bu > CH2Ph ca.CH2CH=CH2 ca.Me > CH2SiMe3 > Ph ca.CH=CH2 > CH2SPh > CCl3 > C6Cl5 > CCPh ca.CCH.