27183-43-3

Basic information

• Product Name: Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-
• Synonyms: Benzene,1,1'-[oxybis(methylene)]bis[3-nitro;1,1'-[oxybis(methylene)]bis[3-nitro-benzene];di(3-nitrobenzyl) ether;Bis-(3-nitro-benzyl)-aether;bis-(3-nitro-benzyl)-ether;Ether,bis(m-nitrobenzyl);Benzene, 1,1‘-[oxybis(methylene)]bis[3-nitro-
• CAS NO: 27183-43-3
• Molecular Formula: C14H12N2O5
• Molecular Weight: 288.26
• Mol File: 27183-43-3.mol
• Article Data: 7

Chemical Properties

• Melting Point: 89.3 °C
• Boiling Point: 457.3±30.0 °C(Predicted)
• Density: 1.353±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-(27183-43-3)
• EPA Substance Registry System: Benzene, 1,1'-[oxybis(methylene)]bis[3-nitro-(27183-43-3)

Safety Data

• Hazardous Substances Data: 27183-43-3(Hazardous Substances Data)

Upstream product

• 309-88-6 hexafluoropropene-diethylamine adduct 
• 619-25-0 3-Nitrobenzyl alcohol 
• 62673-14-7 trimethyl(3-nitrobenzyloxy)silane 
• 99-61-6 3-nitro-benzaldehyde 
• 19479-81-3 (m-nitrophenyl)diazomethane 

Downstream Products

• 619-23-8 3-Nitrobenzyl chloride 

Relevant articles and documents

REACTIONS OF NITRO ALCOHOLS WITH N,N-DIETHYL-1,1,2,3,3,3-HEHAXFUOROPROPYLAMINE

Fluorination of nitro alcohols with N,N-diethyl-1,1,2,3,3,3-hexafluoropropylamine (PPDA) was investigated. 3-Nitrobenzyl fluoride (II) was obtained from the reaction of PPDA and 3-nitrobenzyl alcohol (I) (yield 66 percent).The reaction of 2-methyl-2-nitro

Silica Sulfuric Acid: An Efficient Catalyst for the Direct Conversion of Primary and Secondary Trimethylsilyl Ethers to their Corresponding Ethers under Mild and Heterogeneous Conditions

Primary and secondary trimethylsilyl ethers were converted to their corresponding ethers in the presence silica sulfuric acid with good to excellent yields under mild and heterogeneous conditions.

Reduction of carbonyl compounds promoted by silicon hydrides under the influence of trimethylsilyl-based reagents

The synthetic utility of hydrosilanes under the influence of trimethylsilyl-based reagents as new reducing systems is described. 1,1,3,3-Tetramethyldisiloxane (TMDS) reagent in combination with iodotrimethylsilane or bromotrimethylsilane produces alkyl halides from aldehydes in good to excellent yields.Polymethylhydrosiloxane (PMS) in the presence of iodotrimethylsilane also produces benzyl iodides in excellent yields.On the contrary, PMS reagent was found unsuitable for the synthesis of benzyl bromides.Similary, TMDS reagent in combination with trimethylsilyl triflate produces symmetrical ethers from aldehydes without concomitant formation of competitive products.Under similar conditions, PMS reagent failed to provide the expected symmetrical ethers and Friedel-Crafts products were formed.Reduction of quinones to hydroquinones is also described.