2720-41-4Relevant articles and documents
Nomura,Takeuchi
, p. 1743 (1960)
π-Face-selective hetero Diels-Alder reactions of 3,4-di-tert-butylthiophene 1-oxide. An excellent trapping reagent for thioaldehydes and thioketones
Takayama, Jun,Fukuda, Seiko,Sugihara, Yoshiaki,Ishii, Akihiko,Nakayama, Juzo
, p. 5159 - 5162 (2007/10/03)
Hetero Diels-Alder reactions of 3,4-di-tert-butylthiophene 1-oxide (1) with thioaldehydes and thioketones take place exclusively, except the reaction with thiobenzophenone, at the syn-π-face of 1 with respect to the S=O bond. The π-face selectivity was ex
Gas Phase Reactions, 24. The Thermal Generation of Thiocarbonyl Compounds
Bock, Hans,Hirabayashi, Takakuni,Mohmand, Shamsher
, p. 492 - 503 (2007/10/02)
Thiocarbonyl derivatives R1R2C=S with R1, R2 = H, CH3, C6H5 can be generated thermally in the gas phase from a variety of precursors.Especially advantageous are the cleavage of propene from allyl sulfides or, for their preparation in pure form, the pyrolysis of dithietane or trithiolane derivatives.Photoelectron spectroscopy proves to be well-suited for gas analysis in the flow tube used, for the optimization of the decomposition conditions, and via assignment of the observed ionization patterns for the characterization of the thioaldehydes and thioketones prepared.