27298-57-3Relevant articles and documents
Visible-light-driven selective alkenyl C-P bond cleavage of allenylphosphine oxides
Wei, Kai,Luo, Kai,Liu, Fang,Wu, Lei,Wu, Li-Zhu
, p. 1994 - 1998 (2019/03/29)
An efficient method for highly selective alkenyl C-P bond cleavage, enabled by organic dyes and visible-light irradiation, was developed. This novel protocol involves a highly regioselective radical pathway initiated by singlet oxygen, affording diverse a
Cumulated Trienephosphine Oxides. Bimolecular Trapping of an Alkylidenecyclopropylidene
Santelli-Rouvier, Christiane,Toupet, Lo?c,Santelli, Maurice
, p. 9039 - 9047 (2007/10/03)
Dihalocarbene addition to allenic phosphine oxides occurs mainly at the allylic double bond. Treatment of dibromocarbene adducts with BuLi leads to cumulated trienephosphine oxides. In some cases, the intermediate alkylidenecyclopropylidene (or its precur