27394-83-8

Basic information

• Product Name: 5-(4'-chlorophenyl)-2,4-pentadienol
• Synonyms: 5-(4'-chlorophenyl)-2,4-pentadienol
• CAS NO: 27394-83-8
• Molecular Weight: 192.645
• Mol File: 27394-83-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-(4'-chlorophenyl)-2,4-pentadienol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(4'-chlorophenyl)-2,4-pentadienol(27394-83-8)
• EPA Substance Registry System: 5-(4'-chlorophenyl)-2,4-pentadienol(27394-83-8)

Safety Data

• Hazardous Substances Data: 27394-83-8(Hazardous Substances Data)

Upstream product

• 1047660-78-5 C₁₁H₉ClO 
• 104-88-1 4-chlorobenzaldehyde 
• 110905-37-8 (E)-(4-Oxo-2-butenyl)phosphonsaeure-diethylester 

Relevant articles and documents

Method for preparing olefine aldehyde by catalyzing terminal alkyne or terminal conjugated eneyne and diphosphine ligand used in method

The invention discloses a method for preparing olefine aldehyde by catalyzing terminal alkyne or terminal conjugated eneyne and a diphosphine ligand used in the method. According to the invention, indole-substituted phosphoramidite diphosphine ligand which is stable in air and insensitive to light is synthesized by utilizing a continuous one-pot method, and the indole-substituted phosphoramidite diphosphine ligand and a rhodium catalyst are used for jointly catalyzing to successfully achieve a hydroformylation reaction of aromatic terminal alkyne and terminal conjugated eneyne under the condition of synthesis gas for the first time, so that an olefine aldehyde structure compound can be rapidly and massively prepared, and particularly, a polyolefine aldehyde structure compound which is more difficult to synthesize in the prior art can be easily prepared and synthesized, and a novel method is provided for synthesis and modification of drug molecules, intermediates and chemical products.

New Functionalized Horner-Wadsworth-Emmons Reagents: Useful Building Blocks in the Synthesis of Polyunsaturated Aldehydes. A Short Synthesis of (+/-)-(E,E)-Coriolic Acid

The new Horner-Wadsworth-Emmons reagents 4 and 5 transform carbonyl compounds into 2,4-pentadienals and 3-methyl-2,4-pentadienals, respectively.Reagent 4 gives good yields of the desired products with a variety of aldehydes and ketones; reagent 5 generally gives good yields with aldehydes, but gives lower yields with ketones.The reactions proceed under mild conditions and give the products as predominantly 2E,4E isomers, with moderate to good stereoselectivity.In general, pure samples of the 2E,4E-dienals can be obtained after chromatography.Reagents 4 have been used in the key step in a short synthesis of (+/-)-13-hydroxy-9(E),11(E)-octadecanoic acid ((E,E)-coriolic aicd, 45).