27468-37-7Relevant articles and documents
PHOSPHINE COMPOUND, INTERMEDIATE, PALLADIUM-COMPLEX, AND USE THEREOF
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Page/Page column 43, (2010/02/08)
Palladum-phosphine complexes obtained by reacting a 5 compound of formula (1) below with a palladium compound: F(I) (wherein Ris a hydrogen atom, an alkyl group, a cycloalkyl group or a phenyl group which may be substituted; R and R are each, the same or different, an alkyl group, a cycloalkyl group or a phenyl group which may be substituted; R and R are each, the same or different, a hydrogen atom, an alkyl group, a cycloalkyl group or a phenyl group which may be substituted; R, R, R and R are each, the same or different, an alkyl group, a cycloalkyl group, a phenyl group which may be substituted, an alkoxyl group, a dialkylamino group, a halogen atom, a phenyl group, a benzyl group, a naphthyl group or a halogenated alkyl group; R and R, R and R may be combined to form, each, a fused ring, a trimethylene group, a tetramethylene group or a 20 methylenedioxy group; p, q, r and s are each an integer of 0 to 5; and p + q, and r + s are each in the range of 0 to 5.), which is a novel and efficient catalyst for manufacturing various useful compounds.
Mechanism of Organocalcium Reagent Formation.
Walborsky, H. M.,Hamdouchi, C.
, p. 1187 - 1193 (2007/10/02)
The stereochemistry of the reaction of (S)-(+)-1-bromo- and (S)-(+)-1-chloro-1-methyl-2,2-diphenylcyclopropane and (S)-(+)-1-bromo-1-(methoxymethyl)-2,2-diphenylcyclopropane with calcium-aromatic complexes is reported as is its reaction with a radical clo
