2764-87-6

Basic information

• Product Name: 8,8-dimethyl-8-silabicyclo[4.3.0]nona-1,3,5-triene
• Synonyms: 8,8-dimethyl-8-silabicyclo[4.3.0]nona-1,3,5-triene
• CAS NO: 2764-87-6
• Molecular Formula: C10H14Si
• Molecular Weight: 162.3
• Mol File: 2764-87-6.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 218.9°Cat760mmHg
• Flash Point: 71.6°C
• Appearance: /
• Density: 0.94g/cm³
• Vapor Pressure: 0.181mmHg at 25°C
• Refractive Index: 1.515
• CAS DataBase Reference: 8,8-dimethyl-8-silabicyclo[4.3.0]nona-1,3,5-triene(CAS DataBase Reference)
• NIST Chemistry Reference: 8,8-dimethyl-8-silabicyclo[4.3.0]nona-1,3,5-triene(2764-87-6)
• EPA Substance Registry System: 8,8-dimethyl-8-silabicyclo[4.3.0]nona-1,3,5-triene(2764-87-6)

Safety Data

• Hazardous Substances Data: 2764-87-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H14Si/c1-11(2)7-9-5-3-4-6-10(9)8-11/h3-6H,7-8H2,1-2H3

Upstream product

• 1558-25-4 (chloromethyl)trichlorosilane 
• 6921-34-2 benzylmagnesium chloride 
• 75-16-1 methylmagnesium bromide 
• 20151-87-5 2,2-dichloro-2,3-dihydro-1H-benzo[c]silole 
• 95-47-6 o-xylene 
• 75-78-5 dimethylsilicon dichloride 
• 612-12-4 o-Xylylene dichloride 
• 91-13-4 α,α'-dibromo-o-xylene 
• 89-92-9 2-methylbenzyl bromide 

Downstream Products

• 14019-65-9 1,2-bisbenzene 
• 104454-02-6 2-(hydroxymethyl)benzyl acetate 

Relevant articles and documents

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Rhodium-catalyzed intramolecular silylation of unactivated C(sp 3)-H bonds

The treatment of a variety of hydrosilanes, each incorporating a benzylic C(sp3)-H bond, with a rhodium catalyst resulted in intramolecular dehydrogenative silylation. This silylation reaction was found to occur at typically unreactive C(sp3)-H bonds located at terminal positions on alkyl chains. Interestingly, the rhodium catalyst also promoted regioselective silylation at a site internal to an alkyl chain.

Rates and Mechanism for the Solvolyses of 2,2-Dimethyl-2-sila-1-indanyl Bromide and α-Trialkylsilylbenzyl p-Toluenesulfonates. α-Silicon Effect on the Stability of Benzylic Cations in Solution

α-Silicon effect on the benzylic solvolysis has been investigated.The solvolysis of 2,2-dimethyl-2-sila-1-indanyl bromide in aq acetone exhibits a linear response to the solvent ionizing power YBr, with a slope m close to unity (m = 0.93) and g