27705-07-3

Basic information

• Product Name: methyl 2,3,4,5-tetrahydro-[1,1′-biphenyl]-3-carboxylate
• Synonyms: methyl 2,3,4,5-tetrahydro-[1,1′-biphenyl]-3-carboxylate
• CAS NO: 27705-07-3
• Molecular Weight: 216.28
• Mol File: 27705-07-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2,3,4,5-tetrahydro-[1,1′-biphenyl]-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,4,5-tetrahydro-[1,1′-biphenyl]-3-carboxylate(27705-07-3)
• EPA Substance Registry System: methyl 2,3,4,5-tetrahydro-[1,1′-biphenyl]-3-carboxylate(27705-07-3)

Safety Data

• Hazardous Substances Data: 27705-07-3(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 150131-89-8 3-phenyl-3-cyclohexenecarboxylic acid 
• 591-50-4 iodobenzene 
• 292638-85-8 acrylic acid methyl ester 
• 2288-18-8 2-phenyl-1,3-butadiene 
• 87-66-1 2-hydroxyresorcinol 

Relevant articles and documents

Preparation and reaction chemistry of novel silicon-substituted 1,3-dienes

2-Silicon-substituted 1,3-dienes containing non transferrable groups known to promote transmetallation were prepared by Grignard chemistry and enyne metathesis. These dienes participated in one pot metathesis/Diels-Alder reactions in regio- and diastereoselective fashions. Electron-rich alkenes showed the fastest rates in metathesis reactions, and ethylene, a commonly used metathesis promoter slowed enyne metathesis. 2-Pyridyldimethylsilyl and 2-thienyldimethylsilyl substituted Diels-Alder cycloadducts participated in cross-coupling chemistry and the 2-thienyldimethylsilyl substituted cycloadducts underwent cross-coupling under very mild reaction conditions.