27767-52-8

Basic information

• Product Name: Benzene, [[1-(chloromethylene)-2,2-dimethylpropyl]thio]-, (E)-
• CAS NO: 27767-52-8
• Molecular Formula: C12H15ClS
• Molecular Weight: 226.77
• Mol File: 27767-52-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, [[1-(chloromethylene)-2,2-dimethylpropyl]thio]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [[1-(chloromethylene)-2,2-dimethylpropyl]thio]-, (E)-(27767-52-8)
• EPA Substance Registry System: Benzene, [[1-(chloromethylene)-2,2-dimethylpropyl]thio]-, (E)-(27767-52-8)

Safety Data

• Hazardous Substances Data: 27767-52-8(Hazardous Substances Data)

Upstream product

• 16865-61-5 tert-butyl-2-chloro-acetylene 
• 930-69-8 sodium thiophenolate 
• 917-92-0 3,3-Dimethylbut-1-yne 
• 931-59-9 benzenesulfenyl chloride 
• 131968-42-8 2-{1-[1-Chloro-meth-(E)-ylidene]-2,2-dimethyl-propylsulfanyl}-isoindole-1,3-dione 
• 591-51-5 phenyllithium 

Downstream Products

• 27767-53-9 4r-Chlor-3t-phenylsulfon-2,2-dimethyl-buten-⁽³⁾ 
• 10269-15-5 neopentyl phenyl sulphone 

Relevant articles and documents

Phthalimidesulfenyl Chloride. Part 4. Addition to Acetylenes and Synthetic Utilization of their Adducts

Both the stereo- and regio-chemical reactivity of the phthalimidesulfenyl chloride 1 towards symmetrical and terminal acetylenes and the reactivity of the adducts 3 and 5 with various nucleophiles has been investigated.Nucleophilic substitution of the phthalimide residue was achieved with MeLi, PhLi, ButLi, (Me3Si)2NNa and Me3SiSMe.The synthesis of β-chlorovinyl tributylstannyl sulfides 14 is also described.The synthetic potential of the new sulfur compounds is discussed.