278169-24-7

Basic information

• Product Name: 1-chloro-2,3,4,5-tetraethyl-1-stibole
• Synonyms: 1-chloro-2,3,4,5-tetraethyl-1-stibole
• CAS NO: 278169-24-7
• Molecular Weight: 321.494
• Mol File: 278169-24-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-chloro-2,3,4,5-tetraethyl-1-stibole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-2,3,4,5-tetraethyl-1-stibole(278169-24-7)
• EPA Substance Registry System: 1-chloro-2,3,4,5-tetraethyl-1-stibole(278169-24-7)

Safety Data

• Hazardous Substances Data: 278169-24-7(Hazardous Substances Data)

Upstream product

• 10025-91-9 antimony(III) chloride 

Relevant articles and documents

Synthesis and structure of semi(tetrahydrofuran-O)bispotassium bis(2,3,4,5-tetraethylstibolide)

The reaction of bis(cyclopentadienyl)zircona-2,3,4,5- tetraethylcyclopentadiene (1) with antimony trichloride yields 1-chloro-2,3,4,5-tetraethyl-1-stibole (2). The reduction with potassium gives semi(tetrahydrofuran-O)bispotassium bis(2,3,4,5- tetraethylstibolide) (3). The potassium stibolide columns are linked via K-Sb contacts of 3.618 angstrom, thus forming a wavelike layer structure. The molecular structure shows three crystallographically different metal cations. One potassium atom is located between two stibolide anions, whereas the other ones show additional K-O and K-Sb contacts of 2.681 and 3.618 angstrom, respectively.