27829-71-6

Basic information

• Product Name: 2-Hexenoic acid, ethyl ester, (Z)-
• CAS NO: 27829-71-6
• Molecular Formula: C8H14O2
• Molecular Weight: 142.198
• Mol File: 27829-71-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Hexenoic acid, ethyl ester, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexenoic acid, ethyl ester, (Z)-(27829-71-6)
• EPA Substance Registry System: 2-Hexenoic acid, ethyl ester, (Z)-(27829-71-6)

Safety Data

• Hazardous Substances Data: 27829-71-6(Hazardous Substances Data)

Upstream product

• 123-72-8 butyraldehyde 
• 86980-12-3 2-carbethoxymethyl-4-dimethyl-2-oxo-1,3,2-dioxaphosphorinane 
• 250607-12-6 3-butyroyl-5,5-dimethyloxazolidin-2-one 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 250607-11-5 3-(3'-phenylpropionyl)-5,5-dimethyloxazolidin-2-one 
• 3699-71-6 o-ethyl-phenyl-2-carbethoxymethyl phosphinate 
• 6361-05-3 ethyl 2-(diphenylphosphoryl)acetate 
• 84858-81-1 o-ethyl-butyl-2-carbethoxymethyl phosphinate 
• 6225-95-2 di-n-butyl-2-carbethoxymethyl-phosphine oxide 
• 72258-75-4 2-<(ethoxycarbonyl)methyl>-2-oxo-4,5-dimethyl-1,3,2-dioxaphospholane 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 

Downstream Products

• 59663-70-6 ethyl 3-aminocaproate 
• 134455-46-2 ethyl 3-(benzylamino)caproate 

Relevant articles and documents

First synthesis of 3-S-glutathionylhexanal-d8 and its bisulfite adduct

3-Sulfanylhexan-1-ol (3SH) is an impact odorant of white wines, imparting tropical fruit aromas. A reliable synthetic pathway to 3-S-glutathionylhexanal (glut-3SH-al), a precursor to 3SH that has not been intensively studied, was developed starting from 1-butanol. Application of this synthesis to 1-butanol-d10, conserved eight deuteriums, producing glut-3SH-al-d8, which can be used as an internal standard for future work on the occurrence and evolution of glut-3SH-al in wine systems. Additionally, both glut-3SH-SO3 and glut-3SH-SO3-d8 were synthesised from the corresponding aldehyde, enabling further study of the role of these bisulfite adducts in 3SH biogenesis.

N-acyl-5,5-dimethyl-oxazolidin-2-ones as latent aldehyde equivalents

N-acyl-5,5-dimethyl-oxazolidin-2-ones can function as versatile latent aldehyde equivalents - reductive cleavage with DIBAL-H affords aldehydes in good yield, while tandem DIBAL-H/Wittig methodology affords α,β-unsaturated esters.

THE EFFECT OF THE PHOSPHORYL SUBSTITUENTS ON THE STEREOCHEMISTRY OF THE HORNER REACTION

The stereochemistry of the olefin forming reaction of various phosphoryl stabilized carbanions and aldehydes in ethanol is reported.The aromatic aldehydes react with acyclic phosphoryl stabilized carbanions yielding the trans isomers stereoselectively, whereas the 5- and 6-membered cyclic phosphonates (II and III) resulted in high yields of cis isomeric olefins.The aliphatic aldehydes give rise to considerable amounts of cis olefins also, decreasing in the series phosphonates, phosphinates and phosphine oxides, respectively.The stereochemical results are discussed in terms of pentacoordinated reaction intermediates.