27845-55-2

Basic information

• Product Name: N-benzylidenecyclopropylamine
• Synonyms: N-benzylidenecyclopropylamine
• CAS NO: 27845-55-2
• Molecular Weight: 145.204
• Mol File: 27845-55-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-benzylidenecyclopropylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzylidenecyclopropylamine(27845-55-2)
• EPA Substance Registry System: N-benzylidenecyclopropylamine(27845-55-2)

Safety Data

• Hazardous Substances Data: 27845-55-2(Hazardous Substances Data)

Upstream product

• 13324-66-8 N-benzylcyclopropanamine 
• 100-52-7 benzaldehyde 
• 765-30-0 Cyclopropylamine 
• 100-39-0 benzyl bromide 

Downstream Products

• 2046-18-6 4-phenylbutyronitrile 

Relevant articles and documents

o-Iodoxybenzoic Acid (IBX) as a Viable Reagent in the Manipulation of Nitrogen- and Sulfur-Containing Substrates: Scope, Generality, and Mechanism of IBX-Mediated Amine Oxidations and Dithiane Deprotections

o-Iodoxybenzoic acid (IBX), a highly versatile hypervalent iodine(V) reagent, was found to efficiently mediate the dehydrogenation of amines in addition to facilitating the oxidative cleavage of dithioacetals and dithioketals. Through the development of relevant IBX-based protocols, a plethora of useful synthetic intermediates, including imines, oximes, ketones, and aromatic N-heterocycles, were found to be readily accessible under notably mild conditions. Further investigation of these transformations led to the elucidation of valuable mechanistic details, resulting in the conclusion that they proceed via ionic rather than single electron transfer (SET) pathways.