27872-69-1

Basic information

• Product Name: 2-Pentanone, 4-methyl-3-(phenylthio)-
• CAS NO: 27872-69-1
• Molecular Formula: C12H16OS
• Molecular Weight: 208.324
• Mol File: 27872-69-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Pentanone, 4-methyl-3-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pentanone, 4-methyl-3-(phenylthio)-(27872-69-1)
• EPA Substance Registry System: 2-Pentanone, 4-methyl-3-(phenylthio)-(27872-69-1)

Safety Data

• Hazardous Substances Data: 27872-69-1(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 29585-01-1 3-bromo-4-methyl-2-pentanone 
• 141-79-7 4-methyl-pent-3-en-2-one 
• 882-33-7 diphenyldisulfane 
• 57557-60-5 3-methyl-2-(phenylthio)butanoic acid 
• 917-54-4 methyllithium 
• 108-98-5 thiophenol 
• 61628-47-5 (2-chloromethyl-3-isopropyl-oxiranyl)-trimethyl-silane 
• 75-30-9 2-iodo-propane 
• 5042-53-5 1-(phenylsulfanyl)acetone 

Downstream Products

• 94719-30-9 (2R,3R)-4-Methyl-3-phenylsulfanyl-pentan-2-ol 
• 94719-30-9 (2S,3R)-4-Methyl-3-phenylsulfanyl-pentan-2-ol 
• 63996-52-1 3,4-Dimethyl-3-(phenylthio)-pentan-2-on 

Relevant articles and documents

NUCLEOPHILIC SUBSTITUTION OF α-HALO KETONES. XXI. STRUCTURE-REACTIVITY RELATIONSHIPS IN THE ACETOLYSIS OF 3-SUBSTITUTED 1-CHLORO-3-PHENYLTHIO-2-PROPANONES

The acetolyses of α-chloro ketones 1a-d have been re-investigated under standard conditions and compared with those of the corresponding isomeric substrates 2a-d.It has been shown that participation by the neighbouring phenylthio group, involving a 1-3 shift of the latter, does occur in part even in the case of 1d, while it is the only process in the case of 1e.A few structure-reactivity relationships in the two series of substrates are discussed.