27872-73-7

Basic information

• Product Name: Butanoic acid, 3-oxo-2-(phenylthio)-, ethyl ester
• CAS NO: 27872-73-7
• Molecular Formula: C12H14O3S
• Molecular Weight: 238.307
• Mol File: 27872-73-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Butanoic acid, 3-oxo-2-(phenylthio)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Butanoic acid, 3-oxo-2-(phenylthio)-, ethyl ester(27872-73-7)
• EPA Substance Registry System: Butanoic acid, 3-oxo-2-(phenylthio)-, ethyl ester(27872-73-7)

Safety Data

• Hazardous Substances Data: 27872-73-7(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 609-15-4 ethyl 2-chloro-3-oxo-butyrate 
• 108-98-5 thiophenol 
• 6667-19-2 benzenenesulfenyl dimethylamine 
• 141-97-9 ethyl acetoacetate 
• 1146-42-5 p-methoxyphenylsulfonothioic phenyl ester 
• 7605-25-6 ethyl phenylsulfenylacetate 
• 75-36-5 acetyl chloride 
• 882-33-7 diphenyldisulfane 
• 931-59-9 benzenesulfenyl chloride 
• 258822-89-8 3-Phenylsulfenyl-2-(N-cyanoimino)thiazolidine 
• 16079-15-5 phenylsulfanylium 
• 108362-28-3 4,4-diethoxy-3-phenylthiobut-3-en-2-one 
• 121-44-8 triethylamine 

Downstream Products

• 947239-33-0 C₁₆H₂₃O₆PS 
• 139101-25-0 Ethyl α-fluoro-α-(phenylthio)acetoacetate 
• 95112-79-1 (2R,3S)-3-Hydroxy-2-phenylsulfanyl-butyric acid ethyl ester 
• 95112-80-4 (2S,3S)-3-Hydroxy-2-phenylsulfanyl-butyric acid ethyl ester 
• 882-33-7 diphenyldisulfane 
• 106372-59-2 ethyl 2-fluoro-2-(phenylsulfanyl)acetate 

Relevant articles and documents

Regioselective Mono- and Bis-Sulfenylation of Active Methylene Compounds

Selective mono- and bis-sulfenylation of active methylene groups with a variety of disulfides at an ambient temperature is reported. Sulfenylation is promoted by iodine as a catalyst and sulfenyl iodides as intermediates, under metal-free conditions. The

Synthesis of some novel bioactive 4-oxy/thio substituted-1H-pyrazol-5(4H)-ones via efficient cross-Claisen condensation

α-Oxy/thio substituted-β-keto esters were synthesized through an efficient cross-Claisen condensation of aryl oxy/thio acetic acid ethyl esters with acid chlorides, then it is converted in situ into 4-oxy/thio substituted-1H-pyrazol-5(4H)-ones by the addition of hydrazine or hydrazine derivatives and screened for their antibacterial, antifungal activities.

Electrophilic substitutions with the electrogenerated sulfenium cation R1-S+

The sulfenium cation R1-S+ electrogenerated by oxidation of organic disulfides, reacts with phenols, aromatic ethers and ketones bearing an hydrogen atom in α position, to give alkyl (aryl) sulfanyl compounds.