27943-50-6Relevant articles and documents
A Facile Synthesis of 2-Acetonylcycloalkanones by Using 2-(Halomethyl)-3,5-dioxahex-1-ene
Gu, Xue-Ping,Kirito, Yoichi,Ikeda, Isao,Okahara, Mitsuo
, p. 3390 - 3393 (1990)
-
1,4- and 1,5-Diketones via Palladium-Catalyzed Allylation of Potassium Enoxyborates
Negishi, Ei-ichi,Luo, Fen-Tair,Pecora Anthony J.,Silveira, Augustine
, p. 2427 - 2430 (2007/10/02)
-
3-Chloro-2-(trimethylsiloxy)-1-propene as an Electrophilic Acetonyl Equivalent. A Novel Regioselective Synthesis of 1,4-Dicarbonyl Compounds
Hosomi, Akira,Shirahata, Akihiko,Araki, Yoshitaka,Sakurai, Hideki
, p. 4631 - 4633 (2007/10/02)
α-Metalated imines, hydrazones, and activated methylene compounds are acetonylated with 3-chloro-2-(trimethylsiloxy)-1-propene in high yield.Highly regioselective acetonylation at either the tertiary or secondary α-carbon of 2-methylcyclohexanone can be carried out by selecting the reaction conditions.