28022-22-2Relevant articles and documents
Electrocatalytic Synthesis of gem -Bisarylthio Enamines and α-Phenylthio Ketones via a Radical Process under Mild Conditions
Pan, Yong-Zhou,Cheng, Shi-Yan,Li, Qian-Yu,Tang, Hai-Tao,Pan, Ying-Ming,Meng, Xiu-Jin,Mo, Zu-Yu
supporting information, p. 593 - 600 (2021/03/17)
The novel method for the synthesis of gem -bisarylthio enamines and α-phenylthio ketones was developed via the coupling of α-substituted vinyl azides with thiols in the presence of tetrabutylammonium iodide (TBAI) as a redox catalyst and electrolyte at ro
Synthesis of β-Difluoroalkyl Azides via Elusive 1,2-Azide Migration
Ning, Yongquan,Sivaguru, Paramasivam,Zanoni, Giuseppe,Anderson, Edward A.,Bi, Xihe
supporting information, p. 486 - 496 (2020/02/18)
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Radical Enamination of Vinyl Azides: Direct Synthesis of N-Unprotected Enamines
Ning, Yongquan,Zhao, Xue-Feng,Wu, Yan-Bo,Bi, Xihe
supporting information, p. 6240 - 6243 (2017/11/24)
An electron-withdrawing-group-generable radical-induced enamination of vinyl azides is reported, which results in a variety of β-functionalized N-unprotected enamines in a stereoselective manner. A plausible mechanism involving an unusual 1,3-H transfer of in situ generated iminyl radical intermediate was proposed on the basis of experimental results and DFT calculations.