28042-27-5

Basic information

• Product Name: α-Methylene-4-nitrobenzeneacetic acid methyl ester
• Synonyms: α-Methylene-4-nitrobenzeneacetic acid methyl ester
• CAS NO: 28042-27-5
• Molecular Weight: 207.186
• Mol File: 28042-27-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: α-Methylene-4-nitrobenzeneacetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: α-Methylene-4-nitrobenzeneacetic acid methyl ester(28042-27-5)
• EPA Substance Registry System: α-Methylene-4-nitrobenzeneacetic acid methyl ester(28042-27-5)

Safety Data

• Hazardous Substances Data: 28042-27-5(Hazardous Substances Data)

Upstream product

• 636-98-6 p-nitrobenzene iodide 
• 124582-37-2 methyl 2-(tributylstannanyl)-2-propenoate 
• 13797-13-2 α-(p-nitrophenyl)-β-(N-piperidyl)propionic aicd 
• 34757-14-7 methyl 2-diazopropanoate 
• 586-78-7 para-nitrophenyl bromide 
• 51-80-9 bis-(dimethylamino)methane 
• 2945-08-6 methyl (4-nitrophenyl)acetate 
• 104-03-0 4-nitrobenzeneacetic acid 
• 50-00-0 formaldehyd 
• 4033-88-9 2-(4-nitrophenyl)malonic acid dimethyl ester 
• 67-56-1 methanol 
• 51747-44-5 α-(p-nitrophenyl)acrylic acid 

Downstream Products

• 1431883-53-2 3-(4-nitrophenyl)-6-phenyl-2H-chromen-2-one 
• 1402585-98-1 phenyl 4-(1,2,3-trihydroxypropan-2-yl)phenylcarbamate 
• 1402585-97-0 2-(4-aminophenyl)propane-1,2,3-triol 
• 1402585-96-9 2-(4-nitrophenyl)propane-1,2,3-triol 
• 15121-86-5 2-(4-nitrophenyl)prop-2-en-1-ol 
• 1402581-68-3 1-[[5-tert-butyl-2-(3-chlorophenyl)-2H-pyrazol-3-yl]methyl]-3-[4-[1,2-dihydroxy-1-(hydroxymethyl)ethyl]phenyl]urea 
• 1402581-67-2 1-[[2-(3-chlorophenyl)-5-(trifluoromethyl)-2H-pyrazol-3-yl]methyl]-3-[4-[1,2-dihydroxy-1-(hydroxymethyl)ethyl]phenyl]urea 
• 39718-97-3 methyl 2-(4-aminophenyl)propanoate 
• 104886-06-8 C₁₆H₁₆N₂O₆ 
• 111752-05-7 C₁₈H₂₀N₂O₆ 
• 104886-09-1 1-diazo-3-(4'-nitrophenyl)-4-(pyrrol-1-yl)-2-butanone 
• 104886-14-8 5,6-dihydro-6-(4'-nitrophenyl)-7(8H)-indolizinone 
• 104886-18-2 2-(4'-nitrophenyl)-3-(pyrrol-1-yl)propionic acid 
• 111751-78-1 2-(4-Nitro-phenyl)-3-pyrrol-1-yl-propionic acid methyl ester 

Relevant articles and documents

Palladium-Catalyzed Coupling of an α-Stannyl Acrylate to Aryl Iodides and Triflates. A One-Step Synthesis of Aryl Propenoic Esters.

Aryl iodides undergo a Pd(0)-CuI catalyzed coupling with methyl 3-(tributylstannyl)propenoate to provide the corresponding aryl propenoic esters.Triflates require Pd(0)-CuI-LiCl.

Synthesis of 2-arylacrylic esters from aryl methyl ketones via Wittig reaction/singlet oxygen ene reaction

An efficient synthetic method has been developed for the synthesis of 2-arylacrylic esters from the corresponding aryl methyl ketones via Wittig reaction and singlet oxygen ene reaction. Wittig reaction to aryl methyl ketones with (methoxymethyl)triphenyl

Stabilization of Organic Materials

The invention describes a process for stabilizing an organic material against oxidative, thermal or light-induced degradation, which comprises incorporating therein or applying thereto at least a compound of the formula (I) wherein the general symbols are