28059-65-6

Basic information

• Product Name: N-methyl-N-(2-methylbenzyl)aniline
• Synonyms: N-methyl-N-(2-methylbenzyl)aniline
• CAS NO: 28059-65-6
• Molecular Weight: 211.307
• Mol File: 28059-65-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-methyl-N-(2-methylbenzyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N-(2-methylbenzyl)aniline(28059-65-6)
• EPA Substance Registry System: N-methyl-N-(2-methylbenzyl)aniline(28059-65-6)

Safety Data

• Hazardous Substances Data: 28059-65-6(Hazardous Substances Data)

Upstream product

• 529-20-4 2-methylphenyl aldehyde 
• 100-61-8 N-methylaniline 
• 89-92-9 2-methylbenzyl bromide 

Downstream Products

• 18773-77-8 methyl(phenyl)cyanamide 

Relevant articles and documents

General Reductive Amination of Aldehydes and Ketones with Amines and Nitroaromatics under H2 by Recyclable Iridium Catalysts

Heterogeneous iridium catalysts were prepared and applied for the reductive amination of aldehydes and ketones with nitroaromatics and amines using H2. The iridium catalysts were prepared by pyrolysis of ionic liquid 1-methyl-3-cyanomethylimidazoulium chloride ([MCNI]Cl) with iridium chloride (IrCl3) in activated carbons. Iridium particles were well dispersed and stable in the N-doped carbon materials from [MCNI]Cl with activated carbon. The Ir@NC(600-2h) catalyst was found to be highly active and selective for the reductive amination of aldehydes and ketones using H2 and a variety of nitrobenzenes and amines were selectively converted into the corresponding secondary and tertiary amines. The Ir@NC(600-2h) catalyst can be reusable several times without evident deactivation.

Heterogeneous cobalt catalysts for reductive amination with H2: General synthesis of secondary and tertiary amines

Heterogeneous Co@NC catalysts were prepared, characterized and applied for the reductive amination of aldehydes and ketones with H2 gas. The Co catalyst Co@NC (800-2 h) was found to be active and selective for the reductive amination of aldehydes and ketones using H2 gas. Thus, general synthesis of secondary and tertiary amines was developed by the Co-catalyzed reductive amination with H2 gas, and various secondary and tertiary amines can be obtained in high yields. Moreover, a practical synthesis of N-substituted isoindolinones was also presented by a one step process with the Co@NC (800-2 h) catalyst. The Co@NC (800-2 h) catalyst is reusable at least five times without evident loss of activity.