28122-96-5

Basic information

• Product Name: 3-Pyridinecarbothioic acid, S-phenyl ester
• CAS NO: 28122-96-5
• Molecular Formula: C12H9NOS
• Molecular Weight: 215.276
• Mol File: 28122-96-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Pyridinecarbothioic acid, S-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pyridinecarbothioic acid, S-phenyl ester(28122-96-5)
• EPA Substance Registry System: 3-Pyridinecarbothioic acid, S-phenyl ester(28122-96-5)

Safety Data

• Hazardous Substances Data: 28122-96-5(Hazardous Substances Data)

Upstream product

• 59-67-6 nicotinic acid 
• 108-98-5 thiophenol 
• 10400-19-8 3-pyridinecarbonyl chloride 

Downstream Products

• 35779-35-2 di-3-pyridylmethanone 
• 28856-77-1 3-phenylthiopyridine 

Relevant articles and documents

Fukuyama Cross-Coupling Approach to Isoprekinamycin: Discovery of the Highly Active and Bench-Stable Palladium Precatalyst POxAP

An efficient and user-friendly palladium(II) precatalyst, POxAP (post-oxidative-addition precatalyst), was identified for use in Fukuyama cross-coupling reactions. Suitable for storage under air, the POxAP precatalyst allowed reaction between thioesters and organozinc reagents with turnover numbers of ～90000. A series of 23 ketones were obtained with yields ranging from 53 to 99%. As proof of efficacy, an alternative approach was developed for the synthesis of a key precursor of the natural product isoprekinamycin.