28123-49-1Relevant articles and documents
Addition-type oxidation of silylalkene using ozone: An efficient approach for acyloin and its derivatives
Igawa, Kazunobu,Kawasaki, Yuuya,Tomooka, Katsuhiko
, p. 233 - 235 (2011/05/14)
Acyloins are efficiently synthesized in three steps from alkynes via ydrosilylation followed by an addition-type ozone oxidation and hydrogenation. The key intermediate α-silylperoxy ketone is convertible to not only acyloin but also O-silylated acyloin and diketone.
REDUCTIVE COUPLING OF S-(2-PYRIDYL) ALIPHATIC THIOATES BY USE OF BIS(1,5-CYCLOOCTADIENE)NICKEL
Onaka, Makoto,Matsuoka, Yoshio,Mukaiyama, Teruaki
, p. 905 - 906 (2007/10/02)
S-(2-Pyridyl) aliphatic thioates are reductively dimerized to give α-diketones and α-hydroxy ketones on treatment with bis(1,5-cyclooctadiene)nickel at 40 deg C.