283173-76-2Relevant articles and documents
Pd-catalyzed cascade cyclization by intramolecular heck insertion of an allene-allylic amination sequence: Application to the synthesis of 3,4-fused tricyclic indoles
Nakano, Shun-Ichi,Inoue, Naoya,Hamada, Yasumasa,Nemoto, Tetsuhiro
, p. 2622 - 2625 (2015)
A novel Pd-catalyzed cascade cyclization by intramolecular Heck insertion of an allene-allylic amination sequence was developed. Allenes tethered to ortho-iodoaniline derivatives at the meta-position were reacted with 5-10 mol % of Pd catalyst and 4 equiv
Diphenylacetylene-linked peptide strands induce bidirectional β-sheet formation
Lingard, Hannah,Han, Jeongmin T.,Thompson, Amber L.,Leung, Ivanhoe K. H.,Scott, Richard T. W.,Thompson, Sam,Hamilton, Andrew D.
supporting information, p. 3650 - 3653 (2014/04/17)
In the search for synthetic mimics of protein secondary structures relevant to the mediation of protein-protein interactions, we have synthesized a series of tetrasubstituted diphenylacetylenes that display β-sheet structures in two directions. Extensive