2845-25-2

Basic information

• Product Name: (+)-(S)-3-phenylpentan-1-ol
• Synonyms: (+)-(S)-3-phenylpentan-1-ol
• CAS NO: 2845-25-2
• Molecular Weight: 164.247
• Mol File: 2845-25-2.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: (+)-(S)-3-phenylpentan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(S)-3-phenylpentan-1-ol(2845-25-2)
• EPA Substance Registry System: (+)-(S)-3-phenylpentan-1-ol(2845-25-2)

Safety Data

• Hazardous Substances Data: 2845-25-2(Hazardous Substances Data)

Upstream product

• 1528-59-2 3-phenyl-pent-2-enoic acid ethyl ester 
• 1196-58-3 (1-ethylpropyl)benzene 
• 557-20-0 diethylzinc 
• 824984-08-9 (E)-2,4,6-triisopropyl-N-[(E)-3-phenylallylidene]benzenesulfonamide 
• 93-55-0 1-phenyl-propan-1-one 
• 67478-54-0 ethyl 3-ethyl-3-phenylpropionate 
• 1528-59-2 ethyl (E)-3-phenylpent-2-enoate 
• 14371-10-9 (E)-3-phenylpropenal 
• 137845-37-5 4-methyl-N-((1E,2E)-3-phenylallylidene)benzenesulfonamide 
• 1092461-42-1 N-[(3S)-3-phenylpentanoyl]bornane-10,2-sultam 
• 20068-14-8 (+)-(S)-1-Chlor-2-phenyl-butan 
• 938-79-4 (2R)-2-phenylbutanoic acid 
• 138234-70-5 (4R)-2-((E)-2-Phenylethenyl)-4-phenyl-1,3-oxazolidine 
• 27855-02-3 (3S)-3-Phenylpentanal 

Downstream Products

• 1092461-63-6 (3S)-3-phenyl-1-bromopentane 
• 5354-04-1 4-phenylhexanoic acid 

Relevant articles and documents

Alkyl Ethers as Traceless Hydride Donors in Br?nsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer

A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Br?nsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen-atom donor, and involves an intramolecular hydride transfer as a key step, which is achieved in a regio- and stereoselective manner.

Asymmetric hydrogenation of allylic alcohols using ir?N,P-Complexes

In this study, a series of γ,γ-disubstituted and β,γ-disubstituted allylic alcohols were prepared and successfully hydrogenated using suitable N,P-based Ir complexes. High yields and excellent enantioselectivities were obtained for most of the substrates studied. This investigation also revealed the effect of the acidity of the N,P?Ir-complexes on the acid-sensitive allylic alcohols. DFT ΔpKa calculations were used to explain the effect of the N,P-ligand on the acidity of the corresponding Ir-complex. The selectivity model of the reaction was used to accurately predict the absolute configuration of the hydrogenated alcohols.

Enantioselective isomerization of primary allylic alcohols into chiral aldehydes with the tol-binap/dbapen/ruthenium(II) catalyst

Efficient isomerization: The title reaction was catalyzed by the [RuCl 2{(S)-tol-binap}{(R)-dbapen}]/KOH system in ethanol at 25°C (see scheme). A series of E- and Z-configured aromatic and aliphatic allylic alcohols, including a simple primary alkyl-substituted compound (E)-3-methyl-2-hepten-1-ol, were transformed into the chiral aldehydes with at least 99 % ee. dbapen=2-dibutylamino-1-phenylethylamine, tol-binap=2,2′- bis(di-4-tolylphosphanyl)-1,1′-binaphthyl. Copyright