2847-72-5Relevant articles and documents
Production of liquid hydrocarbon fuels with 3-pentanone and platform molecules derived from lignocellulose
Shen, Tao,Zhu, Chenjie,Tang, Chenglun,Cao, Zhi,Wang, Linfeng,Guo, Kai,Ying, Hanjie
, p. 62974 - 62980 (2016/07/13)
Diesel or jet fuel range C10-C17 branched and cyclic alkanes were produced by reaction of 3-pentanone derived from lactic acid with bio-based aldehydes through aldol condensation followed by hydrodeoxygenation. DBU (1,8-diazabicycloundec-7-ene) was identified as an efficient catalyst for the aldol reaction of 3-pentanone with furan based aldehydes, and the selectivity of single or double aldol condensation product could be easily controlled by adjusting the reaction temperature. For the reaction with aromatic aldehydes, aluminium phosphate demonstrated a higher catalytic activity than DBU and mechanisms were proposed for the difference in the catalytic activity. The final hydrodeoxygenation step could be achieved by using a simple Pd/C + H-beta zeolite system, excellent selectivity was observed under the present system, the clean formation of hydrocarbons with a narrow distribution of alkanes occurred in most cases.
Identification of the Aggregation Pheromone of Flour Beetles Tribolium castaneum and T. confusum (Coleoptera: Tenebrionidae)
Suzuki, Takahisa
, p. 1357 - 1364 (2007/10/02)
The aggregation pheromone produced by the male red flour beetle Tribolium castaneum, and confused flour beetles, T. confusum was identified as 4,8-dimethyldecan-1-al by GLC, GC-MS, PMR spectra, and synthesis of the compound.The synthetic pheromone was less attractive compared with the natural pheromone, because the synthetic sample was composed of four optical isomers.