28582-40-3

Basic information

• Product Name: Cyclohexene, 3-chloro-1-methyl-4-(1-methylethyl)-
• CAS NO: 28582-40-3
• Molecular Formula: C10H17Cl
• Molecular Weight: 172.698
• Mol File: 28582-40-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 3-chloro-1-methyl-4-(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 3-chloro-1-methyl-4-(1-methylethyl)-(28582-40-3)
• EPA Substance Registry System: Cyclohexene, 3-chloro-1-methyl-4-(1-methylethyl)-(28582-40-3)

Safety Data

• Hazardous Substances Data: 28582-40-3(Hazardous Substances Data)

Upstream product

• 4221-98-1 (R)-5-isopropyl-2-methylcyclohexa-1,3-diene 
• 491-04-3 piperitol 
• 491-04-3 trans-6-isopropyl-3-methylcyclohex-2-en-1-ol 

Downstream Products

• 491-04-3 (+)-trans-piperitol 
• 112068-28-7 (3R,4R)-1-methyl-4-(1-methylethyl)-cyclohex-1-en-3-yl acetate 
• 122305-05-9 trans-3-(4-chloro-2-methyl-2(E)-butenyl)-4-isopropyl-1-methylcyclohex-1-ene 

Relevant articles and documents

Microbial Allyl Rearrangement and Resolution of Acetates of Unsaturated Cyclic Terpene Alcohols by Pseudomonas sp. NOF-5 Strain

Microbial hydrolysis of the acetates of unsaturated cyclic terpene alcohols by Pseudomonas sp.NOF-5 isolated from soil was investigated. (+/-)-trans-Carveyl acetate ((+/-)-trans-3) was enantioselectively hydrolyzed with NOF-5 strain to give (-)-trans-carveol ((-)-trans-2 of 86.6percent optical purity).However, the hydrolysis of (+/-)-cis-3 was less enantioselective, while (+/-)-piperitylacetate ((+/-)-6, a cis and trans mixture) was hydrolyzed to give the (-)-trans- and (-)-cis-piperitols ((-)-trans-5 and (-)-cis-5) in a poor optical yield.In this case, other tert-alcohols, (+)-trans- and (-)-cis-2-p-menthen-1-ols ((+/-)-trans-7 and (-)-cis-7, were also produced.Furthermore, microbial and enzymic allyl rearrangements of (+)-trans-6 and (-)-trans-verbenylacetate ((-)-trans-11) were studied.Biological treatment of (+)-trans-6 and (-)-trans-11 with NOF-5 or its esterase gave (+)-trans- and (-)-cis-7 and (+)-cis-3-pinen-2-ol ((+)-cis-12), respectively.