2892-99-1

Basic information

• Product Name: Methanone, (1-methylcyclohexyl)phenyl-
• CAS NO: 2892-99-1
• Molecular Formula: C14H18O
• Molecular Weight: 202.296
• Mol File: 2892-99-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Methanone, (1-methylcyclohexyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (1-methylcyclohexyl)phenyl-(2892-99-1)
• EPA Substance Registry System: Methanone, (1-methylcyclohexyl)phenyl-(2892-99-1)

Safety Data

• Hazardous Substances Data: 2892-99-1(Hazardous Substances Data)

Upstream product

• 2890-61-1 1-methyl-1-cyclohexancarboxylic acid chloride 
• 71-43-2 benzene 
• 100-42-5 styrene 
• 100-52-7 benzaldehyde 
• 1123-25-7 1-methyl-1-cyclohexanecarboxylic acid 
• 865241-08-3 C₁₀H₁₉NO₂ 
• 100-58-3 phenylmagnesium bromide 
• 91-03-2 3-dimethylamino-2-methyl-1-phenyl-propan-1-one 
• 712-50-5 Cyclohexyl phenyl ketone 
• 74-88-4 methyl iodide 
• 57992-31-1 (1-methyl-cyclohex-3-enyl)-phenyl ketone 

Downstream Products

• 1123-24-6 1-methyl-cyclohexylcarboxamide 
• 3183-57-1 1-(1-phenylcyclohexyl)ethanone 
• 100-52-7 benzaldehyde 
• 591-49-1 1-methylcyclohex-1-ene 
• 2919-23-5 cyclobutanol 

Relevant articles and documents

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

The N-heterocyclic carbene-catalyzed radical relay enables the vicinal alkylacylation of styrenes, acrylates and acrylonitrile using aldehydes and tertiary alkyl carboxylic acid-derived redox-active esters. This protocol introduces tertiary alkyl groups and acyl groups to C-C double bonds with complete regioselectivity to produce functionalized ketone derivatives. The radical relay mechanism involves single electron transfer from the enolate form of a Breslow intermediate and radical addition of the resultant alkyl radical to the alkene followed by radical-radical coupling.

Restricted rotation due to the lack of free space within a capsule translates into product selectivity: Photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule

The rotational mobility of organic guest molecules when included within a confined capsule is restricted and this feature could be translated into product selectivity as established with the photochemical behavior of cyclohexyl phenyl ketones. The Royal Society of Chemistry.