2899-58-3

Basic information

• Product Name: Carbamic acid, [2-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)oxy]-2-oxoethyl]-, phenylmethyl ester
• Synonyms: N-(Benzyloxycarbonylamino-acetoxy)-phthalimid;Benzyloxycarbonylamino-acetic acid 1,3-dioxo-1,3-dihydro-isoindol-2-yl ester;N-Benzyloxycarbonyl-glycyl-hydroxyphthalimid-ester;N-Benzyloxycarbonyl-glycin-(N-hydroxy-phthalimidester);Benzyloxycarbonyl-glycin-phthalimidyl-(2)-ester;Benzyloxycarbonyl-glycin-(N-hydroxy-phthalimid-ester);N-(N-benzyloxycarbonyl-glycyloxy)-phthalimide
• CAS NO: 2899-58-3
• Molecular Formula: C18H14N2O6
• Molecular Weight: 354.31400
• Mol File: 2899-58-3.mol
• Article Data: 4

Chemical Properties

• Melting Point: 128 - 129 °C
• CAS DataBase Reference: Carbamic acid, [2-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)oxy]-2-oxoethyl]-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [2-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)oxy]-2-oxoethyl]-, phenylmethyl ester(2899-58-3)
• EPA Substance Registry System: Carbamic acid, [2-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)oxy]-2-oxoethyl]-, phenylmethyl ester(2899-58-3)

Safety Data

• Hazardous Substances Data: 2899-58-3(Hazardous Substances Data)

Upstream product

• 524-38-9 N-hydroxyphthalimide 
• 1138-80-3 N-(Benzyloxycarbonyl)glycine 
• 91837-50-2 N-trichloroacetoxyphthalimide 

Downstream Products

• 13437-63-3 methyl [({[(benzyloxy)carbonyl]amino}acetyl)amino]acetate 
• 41888-85-1 N-(N-benzyloxycarbonyl-glycyl)-DL-phenylalanine methyl ester 
• 76476-13-6 O-(benzyloxycarbonylglycyl)-N-hydroxy-DL-alanine t-butyl ester 
• 138479-39-7 dimethyl 1-hydroxy-1-phenyl-2-N-(N'-benzoxycarbonylglycyl)-aminoethyl-phosphonate 
• 3227-12-1 N--funtumin 

Relevant articles and documents

N-TRICHLOROACETOXYPHTHALIMIDE AS A NEW REAGENT FOR THE SYNTHESIS OF THE N-HYDROXYPHTHALIMIDE ESTERS OF N-PROTECTED AMINO ACIDS

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Photocatalytic decarboxylative alkenylation of α-amino and α-hydroxy acid-derived redox active esters by NaI/PPh3 catalysis

Herein, we report the photocatalytic decarboxylative alkenylation reactions of N-(acyloxy)phthalimide derived from α-amino and α-hydroxy acids with 1,1-diarylethene, and with cinnamic acid derivatives through double decarboxylation, using sodium iodide and triphenylphosphine as redox catalysts. The reaction proceeds under mild irradiation conditions with visible blue light (440 nm or 456 nm) in an acetone solvent without recourse to transition-metal or organic dye based photoredox catalysts. The reaction proceeds via photoactivation of a transiently self-assembled chromophore from N-(acyloxy)phthalimide and NaI/PPh3. Solvation plays a crucial role in the reactivity.