29103-60-4

Basic information

• Product Name: N-[3-[bis(phenylmethyl)amino]phenyl]acetamide
• Synonyms: N-[3-[bis(phenylmethyl)amino]phenyl]acetamide;3-Acetylamino-N,N-dibenzylaniline;N-[3-(N,N-Dibenzylamino)phenyl]acetamide
• CAS NO: 29103-60-4
• Molecular Formula: C₂₂H₂₂N₂O
• Molecular Weight: 330.42288
• EINECS: 249-438-6
• Mol File: 29103-60-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 571°Cat760mmHg
• Flash Point: 299.1°C
• Appearance: /
• Density: 1.172g/cm³
• Vapor Pressure: 4.78E-13mmHg at 25°C
• Refractive Index: 1.657
• CAS DataBase Reference: N-[3-[bis(phenylmethyl)amino]phenyl]acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[3-[bis(phenylmethyl)amino]phenyl]acetamide(29103-60-4)
• EPA Substance Registry System: N-[3-[bis(phenylmethyl)amino]phenyl]acetamide(29103-60-4)

Safety Data

• Hazardous Substances Data: 29103-60-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C22H22N2O/c1-18(25)23-21-13-8-14-22(15-21)24(16-19-9-4-2-5-10-19)17-20-11-6-3-7-12-20/h2-15H,16-17H2,1H3,(H,23,25)

Upstream product

• 99-09-2 3-nitro-aniline 
• 52742-32-2 N,N-dibenzyl-O-benzoylhydroxylamine 
• 103-49-1 dibenzylamine 
• 29103-51-3 N,N-dibenzyl-3-nitroaniline 
• 64-19-7 acetic acid 
• 141-78-6 ethyl acetate 

Relevant articles and documents

A Phosphine-Mediated Dearomative Skeletal Rearrangement of Dianiline Squaraine Dyes

A phosphorus(III)-mediated dearomatization of ortho-substituted dianiline squaraine dyes results in an unusual skeletal rearrangement to provide exotic, highly conjugated benzofuranone and oxindole scaffolds bearing a C3 side chain comprised of a linear conflagration of an enol, a phosphorus ylide, and 2,4-disubstituted aniline. Employing experimental and computational analysis, a mechanistic evaluation revealed a striking dependence on the acidity of the aniline ortho substituent. Notably, the rearrangement adducts underwent rapid and complete reversion to the parent squaraine in the presence of a Br?nsted acid.