29165-34-2Relevant articles and documents
Supramolecular Reinforcement of a Large-Pore 2D Covalent Organic Framework
Alahakoon, Sampath B.,Diwakara, Shashini D.,Dodani, Sheel C.,Fisher, Sarah G.,Gassensmith, Jeremiah J.,Gearhart, Robert L.,Herbert, Fabian C.,McCandless, Gregory T.,Ong, Whitney S. Y.,Smaldone, Ronald A.,Wijesundara, Yalini H.
, (2022/02/09)
Two-dimensional covalent organic frameworks (2D-COFs) are a class of crystalline porous organic polymers that consist of covalently linked, two-dimensional sheets that can stack together through noncovalent interactions. Here we report the synthesis of a
2D-Covalent Organic Frameworks with Interlayer Hydrogen Bonding Oriented through Designed Nonplanarity
Alahakoon, Sampath B.,Tan, Kui,Pandey, Haardik,Diwakara, Shashini D.,McCandless, Gregory T.,Grinffiel, Daniel I.,Durand-Silva, Alejandra,Thonhauser, Timo,Smaldone, Ronald A.
, p. 12987 - 12994 (2020/09/01)
We report the synthesis and characterization of a new class of 2D-covalent organic frameworks, called COFamides, whose layers are held together by amide hydrogen bonds. To accomplish this, we have designed monomers with a nonplanar structure that arises f
Octupolar organometallic Pt(II) NCN-pincer complexes; Synthesis, electronic, photophysical, and NLO properties
Batema, Guido D.,van Walree, Cornelis A.,van Klink, Gerard P.M.,de Mello Donegá, Celso,Meijerink, Andries,Perez-Moreno, Javier,Clays, Koen,van Koten, Gerard
, p. 246 - 252 (2018/02/06)
A series of organometallic octupolar 1,3,5-substituted-2,4,6-styryl-benzene complexes was synthesized by post-modification of parent [PtCl(NCN-CHO-4)], i.e. 1,3,5-tri-R-2,4,6-tris[(4-(PtCl)(3,5-bis[(dimethylamino)methyl]styryl)]benzene (NCN = [C6H2(CH2NMe2)2-2,6]– in which R = OMe, H, Br (1–3). Their synthesis involved a triple Horner-Wadsworth-Emmons reaction of [PtCl(NCN-CHO-4)] with the appropriate tris[(diethoxyphosphoryl)]methyl]benzene derivative. The 195Pt{1H} NMR chemical shift reflects the electronic properties of the π-system to which it is connected. The UV/Vis bands of the octupolar platinum complexes are only slightly red-shifted (by 5–12 nm) with respect to those of corresponding stilbenoid Pt-Cl pincer compounds (i.e., the separate branches), suggesting that there is only a limited electronic interaction between these branches. The fluorescence Stokes shift, quantum yields and lifetimes of 1–3 also are of the same order of magnitude as those of stilbenoid Pt-Cl pincer compounds, indicating that a dipolar excited state is formed, which is localized on one of the three branches. The hyper-Rayleigh scattering technique revealed hyperpolarizabilites βHRS of 430, 870 and 183 × 10?30 esu for 1, 2 and 3, respectively, which are among the highest for transition metal complexes. The highest value was found for the compound lacking a donor or acceptor group at the central core, lending support to the idea that dispersion overwhelms charge transfer in determining the magnitude of the first hyperpolarizability in octupolar compounds.
