292607-11-5Relevant articles and documents
Synthesis of Chlorotrifluoromethylated Pyrrolidines by Electrocatalytic Radical Ene-Yne Cyclization
Ye, Ke-Yin,Song, Zhidong,Sauer, Gregory S.,Harenberg, Johannes H.,Fu, Niankai,Lin, Song
supporting information, p. 12274 - 12279 (2018/08/31)
The stereoselective synthesis of chlorotrifluoromethylated pyrrolidines was achieved using anodically coupled electrolysis, an electrochemical process that combines two parallel oxidative events in a convergent and productive manner. The bench-stable and
Enantioselective IrI-catalyzed carbocyclization of 1,6-enynes by the chiral counterion strategy
Barbazanges, Marion,Auge, Mylene,Moussa, Jamal,Amouri, Hani,Aubert, Corinne,Desmarets, Christophe,Fensterbank, Louis,Gandon, Vincent,Malacria, Max,Ollivier, Cyril
, p. 13789 - 13794 (2012/01/06)
Enantioenriched bicyclo[4.1.0]hept-2-enes were synthesized by Ir I-catalyzed carbocyclization of 1,6-enynes. No chiral ligands were used, CO and PPh3 were the only ligands bound to iridium. Instead, the stereochemical information was
Radical cyclizations terminated by Ir-Catalyzed hydrogen atom transfer
Gansaeuer, Andreas,Otte, Matthias,Shi, Lei
supporting information; experimental part, p. 416 - 417 (2011/04/16)
A system for coupling catalytic radical cyclization and Ir-catalyzed hydrogen atom transfer (HAT) is described. It is essential that the HAT catalyst activates H2 quickly and is not a hydrogenation catalyst. Vaska's complex was found to fulfill both purpo
