292857-23-9

Basic information

• Product Name: (-)-(4S,5R,2'S)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one
• Synonyms: (-)-(4S,5R,2'S)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one
• CAS NO: 292857-23-9
• Molecular Weight: 365.557
• Mol File: 292857-23-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (-)-(4S,5R,2'S)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(4S,5R,2'S)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one(292857-23-9)
• EPA Substance Registry System: (-)-(4S,5R,2'S)-4-(1'-tert-butylpyrrolidin-2'-yl)-5-menthyloxy-4,5-dihydrofuran-2(3H)-one(292857-23-9)

Safety Data

• Hazardous Substances Data: 292857-23-9(Hazardous Substances Data)

Upstream product

• 15185-01-0 N-tert-butyl-pyrrolidine 
• 112968-75-9 (5R)-(L-menthyloxy)-2(5H)-furanone 

Downstream Products

• 526-63-6 (-)-isoretronecanol 

Relevant articles and documents

Highly efficient photochemical addition of tertiary amines to electron deficient alkenes. Diastereoselective addition to (5R)-5-menthyloxy-2[5H]- furanone

Tertiary amines derived from pyrrolidines can be added very efficiently (isolated yields up to 94%) to (5R)-5-mentyloxy-2[5H]-furanone. The addition, which follows a radical chain mechanism initiated by a photoinitiated electron transfer (PET) from the te

Highly efficient and stereoselective radical addition of tertiary amines to electron-deficient alkenes - Application to the enantioselective synthesis of necine bases

A convenient and highly efficient method for the regio- and stereoselective addition of tertiary amines to electron-deficient alkenes has been elaborated. It is based on a radical chain reaction of α-aminyl radicals with alkenes, induced by a photoelectro