29372-98-3Relevant articles and documents
Bulky, spherical, and fluorinated anion BArF induces 'on-water' activity of silver salt for the hydration of terminal alkynes
Saha, Sayantani,Sarbajna, Abir,Bera, Jitendra K.
supporting information, p. 1444 - 1447 (2014/03/21)
AgBArF displays remarkable 'on-water' activity for catalytic hydration of terminal alkynes although it is ineffective in common organic solvents. Liquid alkynes do not require additive or co-solvent whereas a small amount of ethyl acetate triggers quantitative conversions for solid alkynes.
Unusual reaction leading to the formation of dienylamides
Gridnev, I. D.,Balenkova, E. S.
, p. 40 - 42 (2007/10/02)
The reaction of the acetyl fluoroborate-acetonitrile complex with cyclohexene leads at the first stage to the protonated β,γ-unsaturated ketone, which is capable of reacting with acetonitrile to form 3-(1-acetylaminoethylidene)cyclohexene.By changing the order of addition of the reagents it is possible to obtain good yields of dienylamides based on cyclohexane and 1-hexene.
A HIGHLY SELECTIVE ONE-CARBON RING ENLARGEMENT REACTION DIRECTED BY SILICON
Tanino, Keiji,Katoh, Tetsuya,Kuwajima, Isao
, p. 1815 - 1818 (2007/10/02)
On treatment with dichloroaluminium phenoxide, 1-(trimethylsilyl)methylcycloalkanecarbaldehydes undergo selective rearrangement of ring carbons to give the corresponding one-carbon ring enlarged 2-(trimethylsilyl)methylcycloalkanones in excellent yields.
