295338-50-0Relevant articles and documents
Mechanosynthesis of Noels-type NHC-Ruthenium Complexes and Applications in Ring-Opening Metathesis Polymerization
Bantreil, Xavier,Lamaty, Frédéric,Pinaud, Julien,Quintin, Fran?ois
supporting information, (2020/03/05)
The use of ball mills enabled the efficient mechanosynthesis of a variety of N-aryl,N-alkyl imidazolium salts and of corresponding NHC silver(I) complexes. Transmetalation with ruthenium via mechanochemistry allowed the rapid access (from 1.5 min to 1 h)
Expeditious synthesis of N0-substituted N-mesitylimidazolium salts as NHC precursors
Truscott, Byron J.,Klein, Rosalyn,Kaye, Perry T.
experimental part, p. 5041 - 5043 (2011/01/04)
In contrast to time-consuming, conventional thermal approaches, microwave irradiation provides rapid and convenient access to unsymmetrical N0-substituted N-mesitylimidazolium salts, which are important precursors for NHC ligands used in the construction
N-Functionalised heterocyclic carbcne complexes of silver
Tulloch, Arran A. D.,Danopoulos, Andreas A.,Winston, Scott,Kleinhenz, Sven,Eastham, Graham
, p. 4499 - 4506 (2007/10/03)
W-Functionalised imidazol-2-ylidene carbene complexes of Ag1 have been prepared by interaction of the corresponding imidazolium salt with Ag2O in dichloromethane or 1,2-dichloroethane in the presence of molecular sieves or with Ag2CO3 in 1,2-dichloroethane. In an analogous way disilver(i) complexes of o-phenylenedimethylenebis(imidazol-2ylidene) have been obtained. Their structures, as determined by X-ray crystallography, indicate that the carbene ligand ' ' acts as monodentate from the carbene end or as a bridge between two different metal atoms. In one case the silver is coordinated by two carbene ligands. In the majority of the structurally characterised complexes the metal centres adopt linear geometries with M-C(carbene) bond lengths in the range of 207-210 pm characteristic of a single bond. The Royal Society of Chemistry 2000.