29653-27-8Relevant articles and documents
Electrolytic α-Bromination of Some α-Substituted Active Methylene Compounds
Torii, Sigeru,Uneyama, Kenji,Yamasaki, Noritsugu
, p. 819 - 820 (1980)
Electrolytic α-bromination of methyl α-substituted malonates and methyl α-substituted acetoacetates was accomplished in 73-84percent yields in dichloromethane containing tetraethylammonium bromide as an electrolyte and sodium methoxide as an enolizing reagent.
Electrooxidation of malonate and acetylacetate derivatives in the presence of halide ions
Okimoto, Mitsuhiro,Takahashi, Yukio
, p. 2215 - 2219 (2007/10/03)
β-Dicarbonyl compounds, such as dimethyl malonate derivatives and methyl acetoacetate derivatives, were electrooxidized in methanol in the presence of halogen ions to afford the corresponding dimethyl α-halomalonates and methyl α-halocarboxylates. Electrooxidation of bis(β-dimethoxycarbonyl) derivatives similarly afforded cyclic compounds and dihalides.