29667-51-4

Basic information

• Product Name: 1-chloro-2-phenylcyclopropane
• CAS NO: 29667-51-4
• Molecular Weight: 152.623
• Mol File: 29667-51-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-chloro-2-phenylcyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-2-phenylcyclopropane(29667-51-4)
• EPA Substance Registry System: 1-chloro-2-phenylcyclopropane(29667-51-4)

Safety Data

• Hazardous Substances Data: 29667-51-4(Hazardous Substances Data)

Upstream product

• 22985-29-1 1-bromo-1-chloro-2-phenylcyclopropane 
• 42956-39-8 1,1,3-trichloro-3-phenylpropane 
• 2415-80-7 1,1-dichloro-2-phenylcyclopropane 
• 110889-04-8 (3-bromo-3,3-difluoroprop-1-yn-1-yl)triethylsilane 
• 2350-89-2 p-vinylbiphenyl 
• 23020-18-0 (1S,2R)-2-phenylcyclopropanecarboxylic acid 
• 124-41-4 sodium methylate 
• 23691-27-2 1,1,1,3-tetrachloro-3-phenylpropane 

Downstream Products

• 62056-52-4 butyl 3-(trichlorovinyl)-4,5-dihydroisoxazole-5-carboxylate 
• 1188906-47-9 5-phenyl-4-chloroisoxazoline 
• 132337-07-6 Ethyl p-(cis-2-chlorocyclopropyl)benzoate 
• 132337-07-6 Ethyl p-(trans-2-chlorocyclopropyl)benzoate 
• 132337-03-2 p-(cis-2-Chlorocyclopropyl)benzonitrile 
• 132337-03-2 p-(trans-2-Chlorocyclopropyl)benzonitrile 
• 132337-10-1 p-(2-Chlorocyclopropyl)benzoyl chloride 
• 132337-11-2 p-(2-Chlorocyclopropyl)benzamide 
• 78072-76-1 p-(cis-2-Chlorocyclopropyl)acetophenone 
• 78072-76-1 p-(trans-2-Chlorocyclopropyl)acetophenone 
• 132337-09-8 p-(2-Chlorocyclopropyl)benzoic acid 

Relevant articles and documents

Hydrodehalogenation of alkyl halides catalyzed by a trichloroniobium complex with a redox active α-diimine ligand

A high-valent d0 niobium(v) complex, (α-diimine)NbCl3 (1), bearing a dianionic redox-active α-diimine ligand served as a catalyst for a hydrodehalogenation reaction of alkyl halides in the presence of PhSiH3. During the catalytic reaction, the redox-active α-diimine ligand allowed the complex to reversibly release and accept one-electron through switching its coordination mode between a dianionic folded form and a monoanionic planar one.

Olefin cyclopropanations via sequential atom transfer radical addition-dechlorination reactions

In organic synthesis, cyclopropanation reactions are often performed with Simmons-Smith-type reagents or by transition metal catalyzed reactions of olefins with diazo compounds. A novel method for the synthesis of substituted cyclopropanes is described that is based on a two-step reaction sequence. Olefins are reacted with 1,1'-dichlorides in a Ru-catalyzed atom transfer radical addition (ATRA) process and the resulting 1,3-dichlorides are directly converted into cyclopropanes by reductive coupling with magnesium. This one-pot procedure is applicable to a variety of substrates and can be performed in an inter- or intramolecular fashion. Schweizerische Chemische Gesellschaft.

Reductive Carbonylation of gem-Dihalogenocyclopropanes by Pentacarbonyliron(0) in the Presence of Sodium Methoxide

The reaction of gem-dihalogenocyclopropanes derivatives with (tetracarbonyl)(methoxycarbonylato)ferrate(I-) has been investigated; gem-dibromocyclopropanes and gem-chlorobromocyclopropane derivatives are reduced and carbonylated.It could be shown that a bromo ester such as methyl 1-bromo-2-phenylcyclopropanecarboxylate is an intermediate in the transformation of 1,1-dibromo-2-phenylcyclopropane into methyl cis- and trans-2-phenylcyclopropanecarboxylates and dimethyl 2-phenyl-1,1-cyclopropanedicarboxylate.