29844-85-7

Basic information

• Product Name: 2,5-Methano-1H-indene, 2,3,3a,4,5,7a-hexahydro-
• CAS NO: 29844-85-7
• Molecular Formula: C10H14
• Molecular Weight: 134.221
• Mol File: 29844-85-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,5-Methano-1H-indene, 2,3,3a,4,5,7a-hexahydro-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Methano-1H-indene, 2,3,3a,4,5,7a-hexahydro-(29844-85-7)
• EPA Substance Registry System: 2,5-Methano-1H-indene, 2,3,3a,4,5,7a-hexahydro-(29844-85-7)

Safety Data

• Hazardous Substances Data: 29844-85-7(Hazardous Substances Data)

Upstream product

• 18971-91-0 2-iodoadamantane 
• 7314-85-4 2-adamantyl bromide 
• 768-90-1 1-Adamantyl bromide 
• 67-56-1 methanol 
• 39257-31-3 1,2-di-iodoadamantane 

Downstream Products

• 25139-43-9 2-adamantyl tosylate 
• 75031-72-0 exo-4-protoadamantyl-5-d 3,5-dinitrobenzoate 
• 19213-98-0 4^a-bromoadamantan-2-one 
• 19213-99-1 2,4-Dihydroxyadamantane 

Relevant articles and documents

More on adamantene

At high dilution and temperature adamantene undergoes a retro Diels - Alder cycloaddition to a triene, as well as retro-insertion reactions to give carbenes. 1,2-Diiodoadamantane and 3-diiodomethylnoradamantane react with methyllithium in the gas phase to give adamantene, which is efficiently reduced to adamantane under these conditions. Addition of adamantene to butadiene occurs in 4 + 2 and 2 + 2 fashion.

REACTION OF 1-BROMOADAMANTANE WITH AN ALCOHOL SOLUTION OF ALKALI

The main direction in the reaction of 1-bromotricyclo3,7>decane with an alcohol solution of potassium hydroxide is solvolysis with the formation of tricyclo3,7>decan-1-ol and tricyclo3,8>decan-3-ol.Dehydrobromination takes place to a lesser degree, leading to tetracyclo3,7.02,4>decane and tricyclo3,8>dec-4-ene.