30034-76-5

Basic information

• Product Name: Benzene,1,1'-(1,1,2,2-tetramethyl-1,2-ethanediyl)bis[4-nitro-
• Synonyms: NSC 87330
• CAS NO: 30034-76-5
• Molecular Formula: C18H20 N2 O4
• Molecular Weight: 328.368
• Mol File: 30034-76-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene,1,1'-(1,1,2,2-tetramethyl-1,2-ethanediyl)bis[4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene,1,1'-(1,1,2,2-tetramethyl-1,2-ethanediyl)bis[4-nitro-(30034-76-5)
• EPA Substance Registry System: Benzene,1,1'-(1,1,2,2-tetramethyl-1,2-ethanediyl)bis[4-nitro-(30034-76-5)

Safety Data

• Hazardous Substances Data: 30034-76-5(Hazardous Substances Data)

Upstream product

• 14500-58-4 4-nitrocumyl chloride 
• 22600-93-7 sodium salt of diethyl butylmalonate 
• 3276-35-5 2-nitro-2-(4-nitrophenyl)propane 
• 116248-38-5 1-methyl-4-phenylsulfonylmethyl-5-nitro-1H-imidazole 
• 80866-17-7 4-nitrocumyl radical 
• 39980-20-6 dimethyl (4-nitrobenzyl)phosphonate 
• 70951-50-7 α,α-dimethyl 4-nitrobenzylbromide 
• 71591-75-8 sodium 2-mercaptothiazolinate 
• 2492-26-4 sodium 2-mercaptobenzothiazole 
• 1889-67-4 dicumene 

Relevant articles and documents

A new synthetic approach for novel 4-substituted-5-nitroimidazoles

A new synthetic approach, involving an SRN1 reaction of the anion of 1-methyl-4-phenylsulfonyl-methyl-5-nitro-1H-imidazole with 2,2-dinitropropane and a radical anion or a concerted radical reductive elimination of sulfonyl and nitro groups affords an original 5-nitroimidazole bearing a trisubstituted ethylenic double bond at 4-position.

A facile preparation of dialkyl phosphonate compounds from sterically hindered p-nitrocumyl halides through the S(RN)1 mechanism

p-Nitrobenzyl phosphonate anion with p-nitrocumyl halides gives a good yield of the coupling product dialkyl[(1,1-dimethyl-1,2-di-(p- nitrobenzyl)ethyl] phosphonates through the S(RN)1 mechanism. The reaction was greatly accelerated by sunlamp irradiation but inhibited by the radical scavenger (t-Bu)2NO..

REACTIVITY OF HETEROCYCLIC AMBIENT S...N ANIONS IN SRN1 SUBSTITUTION REACTIONS

Ambident anions of 2-mercaptoazoles react, under photo- stimulation conditions, with α,p-dinitrocumene according to an SRN1 mechanism (short chain) leading to S-alkylated compounds in agreement with a kinetically controlled reaction.Regioselect