30068-53-2

Basic information

• Product Name: 2-bromo-1-phenyl-1H-pyrrole
• Synonyms: 2-bromo-1-phenyl-1H-pyrrole
• CAS NO: 30068-53-2
• Molecular Weight: 222.084
• Mol File: 30068-53-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-bromo-1-phenyl-1H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-1-phenyl-1H-pyrrole(30068-53-2)
• EPA Substance Registry System: 2-bromo-1-phenyl-1H-pyrrole(30068-53-2)

Safety Data

• Hazardous Substances Data: 30068-53-2(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 38480-28-3 2-bromo-1H-pyrrole 
• 635-90-5 1-phenylpyrrole 
• 667-27-6 Ethyl bromodifluoroacetate 
• 685-87-0 Diethyl 2-bromomalonate 

Relevant articles and documents

LIGHT-EMITTING MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE, ORGANIC ELECTROLUMINESCENT DEVICE USING SAME, AND MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE

Disclosed are a fused compound having excellent emission wavelength control and luminous efficiency, a method for manufacturing the same, and an organic electronic device including the fused compound. Symmetric, asymmetric, and planar structures of the pr

A Heteroarylamine Library: Indium-Catalyzed Nucleophilic Aromatic Substitution of Alkoxyheteroarenes with Amines

Under indium Lewis acid catalysis, electron-rich five-membered heteroaryl electrophiles fused with/without a benzene ring were found to couple with amines to produce heteroarylamines with broad structural diversity. The heteroarylamine formation proceeds through the cleavage of a heteroaryl?OMe bond by the nucleophilic attack of the amine based on the nucleophilic aromatic substitution (SNAr) reaction. In contrast to the corresponding traditional SNAr amination, the present SNAr-based heteroaryl amination can be performed without relying on both heteroaryl electrophiles with electron-withdrawing groups and nucleophilicity-enhanced metal amides. High compatibility towards the functional groups such as NO2, Br, I, CF3, CN, CO2Et, pyridyl, thiazolyl, C=C, and OH groups was observed, thus showing the practicality and reliability of this method. Mechanistic studies indicated that a carbon?indium bond is likely to be formed on the heteroaryl ring during the process. (Figure presented.).

Bromination and Chlorination of Pyrrole and Some Reactive 1-Substituted Pyrroles

Monobromination of pyrrole and 1-methyl-, 1-benzyl-, and 1-phenylpyrrole with 1 mol of N-bromosuccinimide in tetrahydrofuran results in the regiospecific formation of the 2-bromopyrroles.A little disubstitution is observed.Similarly, brominations with 2, 3, or 4 mol of NBS form primarily the di-, tri-, and tetrabromopyrroles, respectively.The thermodynamically more stable 3-bromopyrroles are the major monobrominated products observed when bromine is used as the brominating agent due to isomerization of the 2-bromopyrroles with hydrogen bromide.These reaction mixtures are further complicated because of disproportionation reactions.Chlorination with N-chlorosuccinimide gave results similar to those for the bromination with NBS, but the reaction is not as selective.