300773-40-4

Basic information

• Product Name: cis-[PdCl(2-(diphenylphosphinoamino)pyridine-P,N)(P(OMe)3)]Cl
• CAS NO: 300773-40-4
• Molecular Weight: 579.696
• Mol File: 300773-40-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-[PdCl(2-(diphenylphosphinoamino)pyridine-P,N)(P(OMe)3)]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: cis-[PdCl(2-(diphenylphosphinoamino)pyridine-P,N)(P(OMe)3)]Cl(300773-40-4)
• EPA Substance Registry System: cis-[PdCl(2-(diphenylphosphinoamino)pyridine-P,N)(P(OMe)3)]Cl(300773-40-4)

Safety Data

• Hazardous Substances Data: 300773-40-4(Hazardous Substances Data)

Upstream product

• 17787-26-7 cis-[PdCl₂(P(OMe)3)2] 
• 29938-19-0 2-((diphenylphosphino)amido)pyridine 

Relevant articles and documents

The co-ordination chemistry of 2-(diphenyIphosphinoamino)pyridine 1

2-(Diphenylphosphinoamino)pyridine, dppap [Ph2PNHpy], and over 40 illustrative examples of its complexes have been prepared. Monodentate, bidentate and bridging co-ordination of the neutral (and bidentate deprotonated ligand) has been demonstrated in a range of palladium, platinum and gold complexes. Ten demonstrative examples have been characterised by single crystal X-ray diffraction. Ph2PNHpy exists as hydrogen-bonded dimer pairs; cis[PtCl(Ph2PNHpy-P,Ar){Ph2PNHpy-P}]Cl packs in hydrogen-bonded infinite chains; cis-[PtCPh2PNpy-.P.A2] and cis-[Pd(Ph2PNpy-P,N)2] are isomorphous. The structures of cis-[Pd(Ph2PNHpy-P,N)2][BF4]2, [AuCl(Ph2PNHpy-.P)], [Pt(C8H12OMe)(Ph2PNpy-P,N)]-H2O illustrating hydrogen-bonding, cis-[PtCl(Ph2PNHpy-P,N)(PMe3)]Cl, cis[PtCl(Ph2PNpy-P,N(PMe3)] and cis-[PtCl(Ph2PNHpy-P,N)(P(OPh)3)]Cl are also reported. The Royal Society of Chemistry 2000.