301329-93-1

Basic information

• Product Name: Benzene, 1-nitro-3-(phenylseleno)-
• CAS NO: 301329-93-1
• Molecular Formula: C12H9NO2Se
• Molecular Weight: 278.169
• Mol File: 301329-93-1.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-3-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-3-(phenylseleno)-(301329-93-1)
• EPA Substance Registry System: Benzene, 1-nitro-3-(phenylseleno)-(301329-93-1)

Safety Data

• Hazardous Substances Data: 301329-93-1(Hazardous Substances Data)

Upstream product

• 71098-88-9 N-phenylselanylphthalimide 
• 13331-27-6 m-nitrobenzene boronic acid 
• 2179-79-5 phenyl selenocyanate 
• 1666-13-3 diphenyl diselenide 
• 99-09-2 3-nitro-aniline 
• 34837-55-3 Phenylselenyl bromide 
• 586-36-7 3-nitrophenyldiazonium tetrafluoroborate 
• 121-73-3 3-Nitrochlorobenzene 
• 645-00-1 m-iodonitrobenzene 
• 41924-21-4 phenyl tributylstannyl selenide 
• 591-50-4 iodobenzene 
• 51516-96-2 3-nitrophenylhydrazine hydrochloride 

Relevant articles and documents

Metal-Free Synthesis of Unsymmetrical Aryl Selenides and Tellurides via Visible Light-Driven Activation of Arylazo Sulfones

A protocol for the visible light driven preparation of unsymmetrical (hetero)aryl selenides and tellurides is described herein. The method exploits the peculiar photoreactivity of arylazo sulfones that act as thermally stable, precursors of aryl radicals under both photocatalyst- and additive-free conditions. The method developed shows an impressive versatility (more than fifty compounds isolated).

Efficient heterogeneous copper-catalysed C–Se coupling of aryl iodides with symmetrical diselenides towards unsymmetrical monoselenides

A highly efficient heterogeneous copper(I)-catalysed C–Se coupling of aryl iodides with diaryl diselenides was achieved in dimethylformamide at 110 °C under neutral conditions by using a 10 mol% of bipyridine-functionalised MCM-41-supported copper(I) complex [bpy-MCM-41-CuI] as the catalyst and magnesium as the reductive reagent, yielding a variety of unsymmetrical diaryl selenides in good to excellent yields. This heterogeneous copper catalyst can be easily recovered by a simple filtration of the reaction solution and recycled at least seven times without significant loss of activity.

Silver-catalyzed carbon-selenium cross-coupling using N-(phenylseleno)phthalimide: An alternate approach to the synthesis of organoselenides

Silver(I) catalyzed phenylselenylation of terminal alkynes and organoboronic acids has been demonstrated using N-(phenylseleno)phthalimide as an electrophilic SePh donor. A wide variety of terminal alkynes and organoboronic acids are selenylated efficiently to produce the corresponding alkynyl and diaryl selenides, respectively, in good yields. Silver(I) acts as a Lewis acid in this process.