30263-10-6Relevant articles and documents
N,N-Dimethylformamide-protected Fe2O3 Combined with Pt Nanoparticles: Characterization and Catalysis in Alkene Hydrosilylation
Nagata, Tatsuki,Tanaka, Tatsuya,Lin, Xianjin,Kondo, Ryota,Suzuki, Takeyuki,Kanda, Yasuharu,Toyao, Takashi,Shimizu, Ken-ichi,Obora, Yasushi
, (2021/11/30)
We report a combination of N,N-dimethylformamide (DMF)-protected Fe2O3 nanoparticles (NPs) and Pt NPs for the hydrosilylation of various industrially relevant alkenes and tertiary silanes. The DMF-protected Fe2O3 and Pt NPs catalysts were characterized by transmission electron microscopy, X-ray absorption spectroscopy, and X-ray photoelectron spectroscopy. The catalyst of DMF-protected Fe2O3 NPs combined with Pt NPs can be recycled for five cycles by a simple extraction using hexane/DMF. The developed combination Fe2O3/Pt NPs catalyst is effective up to the 1-kilogram scale.