30358-01-1Relevant articles and documents
Zinc base assisted amination of 2-chloropyrimidines by aniline derivatives at room temperature
Delvos, Lukas B.,Begouin, Jeanne-Marie,Gosmini, Corinne
supporting information; experimental part, p. 2325 - 2328 (2011/11/06)
The amination of 2-chloropyrimidines was performed with several aniline derivatives in the presence of tolylzinc bromide as a base. The organozinc compound has a profound effect on the reactivity of the amines, so that the reaction takes place at room tem
Synthesis, structure, and dynamic behavior in solution of arylamino-1,3,5-triazines. 1. Unsymmetrically substituted arylamino-1,3,5- triazines
Belyakov,Shatin,Strelenko
, p. 2441 - 2451 (2007/10/03)
Ten unsymmetrically substituted arylamino-1,3,5-triazines were synthesized and studied by dynamic NMR spectroscopy. The free energies of the hindered rotation ΔG≠ are in 59-77 kJ mol-1 range. Using difference-mode NOE NMR experiments
MANGANESE DIOXIDE OXIDATION OF HYDROXYAMINO-sym-TRIAZINES
Sedova. V. F.,Shkurko, O. P.
, p. 593 - 597 (2007/10/02)
The hydroxyamino group in sym-triazines is readily oxidized by the action of manganese dioxide.The stability of the nitrosotriazines formed in this oxidation depends on the electron donor properties of the other substituents in the molecule.