30414-28-9Relevant articles and documents
CATYLYTIC SYNTHESIS AND REACTIONS OF MAGNESIOCYCLOALKANES. 2. SYNTHESIS OF SUBSTITUTED MAGNESIOCYCLOPENTANES IN THE PRESENCE OF ZYRCONIUM COMPLEXES
Dzhemilev, U. M.,Sultanov, R. M.,Gaimaldinov, R. G.,Muslukhov, R. R.,Lomakina, S. I.,Tolstikov, G. A.
, p. 770 - 788 (2007/10/02)
Catalytic cyclometallation of styrene, m-methylstyrene, p-tert-butylstyrene, and 1-hexene with di n-alkylmagnesium compounds (n-R2Mg, where R=C3H7, C4H9, C6H13) in the presence of Cp2Zr2Cl2 has been given high yields of 2,4-disubstituted magnesiocyclopentanes.The probable mode of formation of magnesiocyclopentanes, involving zirconocyclopentanes formed from Cp2ZrCl2, n-R2Mg, and the appropiate olefins as reactive intermediates in the cyclometallation, is discussed. Keywords: catalytic synthesis, substituted styrenes, alkenes, magnesium alkyls.
BASE INDUCED REACTION OF SILACYCLOBUTANE WITH ALDEHYDE OR EPOXIDE
Takeyama, Yoshihiro,Oshima, Koichiro,Utimoto, Kiitiro
, p. 6059 - 6062 (2007/10/02)
The reaction of silacyclobutane with benzaldehyde in the presence of a catalytic amount of potassium t-butoxide gave six-membered cyclic silyl ether.Meanwhile, treatment of a mixture of silacyclobutane and epoxide with lithium diisopropylamide provided si