30506-33-3Relevant articles and documents
Thioether ligand-enabled cationic palladium (II)-catalyzed electrophilic C-H arylation of α,β-unsaturated oxime ethers
Tamura, Osamu,Yamada, Takahiro,Hashimoto, Yoshimitsu,Tanaka Iii, Kosaku,Morita, Nobuyoshi
, p. 12315 - 12328 (2020/11/10)
The use of the cationic palladium(II) catalyst realized electrophilic C-H arylation of α,β-unsaturated O-SEM oximes with arylboronic acids. This Pd-catalyzed electrophilic C-H arylation is facilitated by employing alkyl aryl thioether ligands, and optimization of the ligand structure greatly improves the yield. The resulting α,β-unsaturated oximes would provide access to multisubstituted heterocyclic compounds.
Copper-Catalyzed Three-Component Coupling Reaction of Aryl Iodides, a Disilathiane, and Alkyl Benzoates Leading to a One-Pot Synthesis of Alkyl Aryl Sulfides
Sakai, Norio,Maeda, Hiromu,Ogiwara, Yohei
, p. 2323 - 2330 (2019/05/24)
A copper-catalyzed three-component coupling reaction of aryl iodides, hexamethyldisilathiane and alkyl benzoates leading to alkyl aryl sulfides has been demonstrated. A disilathiane acted as both a sulfur source and a promoter of the sulfidation, and the alkyl moiety of the alkyl benzoate was effectively introduced on one side of the sulfide. Moreover, we found that the protocol can be expanded to the preparation of ethyl phenyl selenide with diphenyl diselenide.
Cyclodextrin-Mediated Chiral Sulfoxidations
Czarnik, Anthony W.
, p. 924 - 927 (2007/10/02)
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