30516-22-4

Basic information

• Product Name: 1-(2-chlorobenzyl)-1H-benzo[d][1,2,3]triazole
• Synonyms: 1-(2-chlorobenzyl)-1H-benzo[d][1,2,3]triazole;1-[(2-Chlorophenyl)methyl]-1H-1,2,3-benzotriazole
• CAS NO: 30516-22-4
• Molecular Formula: C₁₃H₁₀ClN₃
• Molecular Weight: 243.6916
• Mol File: 30516-22-4.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-(2-chlorobenzyl)-1H-benzo[d][1,2,3]triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-chlorobenzyl)-1H-benzo[d][1,2,3]triazole(30516-22-4)
• EPA Substance Registry System: 1-(2-chlorobenzyl)-1H-benzo[d][1,2,3]triazole(30516-22-4)

Safety Data

• Hazardous Substances Data: 30516-22-4(Hazardous Substances Data)

Upstream product

• 54187-96-1 1-(chloromethyl)-1H-benzotriazole 
• 108-90-7 chlorobenzene 
• 95-14-7 1,2,3-Benzotriazole 
• 611-19-8 1-chloro-2-(chloromethyl)benzene 
• 1262319-59-4 C₁₉H₁₃ClN₆ 
• 1334478-54-4 Br^(1-)*C₂₀H₁₆Cl₂N₃⁽¹⁺⁾ 

Downstream Products

• 196861-96-8 1-[1-(2-Chloro-phenyl)-2-trimethylsilanyl-ethyl]-1H-benzotriazole 
• 196862-09-6 3-Benzotriazol-1-yl-3-(2-chloro-phenyl)-1-phenyl-4-trimethylsilanyl-butan-1-ol 

Relevant articles and documents

Reactivity of AllylSmBr/HMPA: Facile Synthesis of 3-Aryl-1,2,4- benzotriazines

3-Aryl-1,2,4-benzotriazines were conveniently prepared in moderate to good yields from 1,l-bis(benzotriazol-1-yl)methylarenes with allylsamarium bromide/hexamethylphosphramide (allylSmBr/HMPA). Preliminary results indicate that HMPA may enhance the reduci

Construction of 3-aryl-1,2,4-benzotriazines via unprecedented rearrangement of bis(benzotriazol-1-yl)methylarenes

3-Aryl-1,2,4-benzotriazines were formed unexpectedly by the treatment of 1,l-bis(benzotriazol-1-yl)methylarenes with allylsamarium bromide. A radical pathway was proposed involving steps, such as fragmentation, ring-opening, and cyclization.

Mannich/Friedel-Crafts Preparations of 1-(Arylmethyl)benzotriazoles and Synthetic Transformations of their Lithio Derivatives

The synthesis of 1-(arylmethyl)benzotriazoles by Mannich type reactions of benzene, toluene, p-xylene and chlorobenzene with 1-chloromethylbenzotriazole in the presence of aluminium halides is reported.Alkylation of their lithio derivatives followed by th