30545-31-4Relevant articles and documents
Solvent-dependent competitive rearrangements of cyclic tertiary propargylamine N-oxides
Szabo, Anna,Galstnibos-Farago, Agnes,Mucsi, Zoltan,Timari, Geza,Vasvari-Debreczy, Lelle,Hermecz, Istvan
, p. 687 - 694 (2007/10/03)
In protic media, cyclic propargylamine N-oxides 1 undergo solvent-dependent competitive rearrangements leading to enamino aldehydes 5, acrylamides 3, and secondary amines 4. The ratios of the products are evaluated and the possible mechanism of the compet