305815-25-2

Basic information

• Product Name: (E)-1-(allyloxy)-4-(prop-1-en-1-yl)benzene
• Synonyms: (E)-1-(allyloxy)-4-(prop-1-en-1-yl)benzene
• CAS NO: 305815-25-2
• Molecular Weight: 174.243
• Mol File: 305815-25-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (E)-1-(allyloxy)-4-(prop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(allyloxy)-4-(prop-1-en-1-yl)benzene(305815-25-2)
• EPA Substance Registry System: (E)-1-(allyloxy)-4-(prop-1-en-1-yl)benzene(305815-25-2)

Safety Data

• Hazardous Substances Data: 305815-25-2(Hazardous Substances Data)

Upstream product

• 40663-68-1 4-(2-propenyloxy)benzaldehyde 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 123-08-0 4-hydroxy-benzaldehyde 
• 123-38-6 propionaldehyde 
• 109-77-3 malononitrile 
• 16215-47-7 3-(4-vinylphenyloxy)-1-propene 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 20649-39-2 (E)-1-(4-hydroxyphenyl)propene 
• 106-95-6 allyl bromide 
• 106-41-2 4-bromo-phenol 
• 70-70-2 4-hydroxypropiophenone 
• 305815-24-1 4-(1-hydroxypropyl)phenyl ether 
• 2089-23-8 allyl 4-propionylphenyl ether 

Downstream Products

• 1369494-79-0 (Z)-1-allyloxy-4-(prop-1-en-1-yl)benzene 
• 40663-68-1 4-(2-propenyloxy)benzaldehyde 

Relevant articles and documents

A PMMA-based heterogeneous photocatalyst for visible light-promoted [4 + 2] cycloaddition

Macromolecular organic photocatalysts consisting of a completely conjugated network have broad and promising applications in visible light-promoted photoredox catalysis. Precise reproduction and control of exact conjugation length remains an important challenge for fully conjugated and macromolecular photocatalysts. Here, we introduce a new photocatalytic material based on classical PMMA copolymerised with defined electron donor and acceptor units with precisely controllable redox potential and conjugation length, creating a promising class of metal-free, stable and low-cost heterogeneous photocatalysts. Furthermore, swelling of the PMMA copolymer matrix in organic solvents led to enhanced substrate diffusion and thereby increased catalytic efficiency. High efficiency and selectivity was achieved for photocatalytic [4 + 2] cycloaddition reactions in air with low effective photocatalyst loading. The photocatalytic efficiency of the PMMA photocatalyst was comparable with the state-of-the-art metal or non-metal catalysts while facilitating easy recyclability.

SINGLE-STEP PROCESS FOR THE PREPARATION OF ARYL OLEFINS

The present invention relates to the single-step process for the synthesis of aryl olefin compounds of Formula (1) by reacting aryl aldehydes with alkyl aldehydes in presence of malononitrile and acid or base or salt, optionally in presence of solvent.

Expanding the regioselective enzymatic repertoire: Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

The first report of a biocatalytic regioselective oxidative mono-cleavage of dialkenes was successfully achieved employing a cell-free enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities. The Royal Society of Chemistry 2012.