306763-43-9

Basic information

• Product Name: 1,2-Ethanediol, 1-(4-bromophenyl)-, 2-acetate, (1R)-
• CAS NO: 306763-43-9
• Molecular Formula: C10H11BrO3
• Molecular Weight: 259.1
• Mol File: 306763-43-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,2-Ethanediol, 1-(4-bromophenyl)-, 2-acetate, (1R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Ethanediol, 1-(4-bromophenyl)-, 2-acetate, (1R)-(306763-43-9)
• EPA Substance Registry System: 1,2-Ethanediol, 1-(4-bromophenyl)-, 2-acetate, (1R)-(306763-43-9)

Safety Data

• Hazardous Substances Data: 306763-43-9(Hazardous Substances Data)

Upstream product

• 108-22-5 Isopropenyl acetate 
• 7500-37-0 2-(4-bromophenyl)-2-oxoethyl acetate 
• 108-86-1 bromobenzene 
• 4209-02-3 1-(4-bromophenyl)-2-chloroethan-1-one 
• 108-05-4 vinyl acetate 
• 92093-23-7 1-(4-bromophenyl)ethane-1,2-diol 

Downstream Products

• 92093-23-7 (R)-(-)-1-(4-bromophenyl)-1,2-ethanediol 

Relevant articles and documents

Chemoenzymatic synthesis of enantiomerically pure 1,2-diols employing immobilized lipase in the ionic liquid [bmim]PF6

Significantly enhanced enantioselectivity in the enzymatic kinetic resolution of 1,2-diols employing immobilized lipase from Pseudomonas cepacia (PS-C, 'Amano') results from the use of the ionic liquid [bmim]PF6 as reaction medium.

Baker's yeast-mediated reduction of α-hydroxy ketones and derivatives: The steric course of the biotransformation

The results from the baker's yeast-mediated reduction of the acetates 3a- d and the methyl ethers 5a-d were compared with the same biotransformation which converts the α-hydroxy ketones 1a-d into the (R)-diols 2a-d (90- 98%ee); the acetates 3a-d afford the (S)-monoacetates 4a-d (72-94% ee) and the methyl ethers 5a-d are reduced to the (R)-monoethers 6a-d (64-76% ee).